RT Journal Article
T1 New directions in metal phosphonate and fhosphinate chemistry
A1 Shearan, Stephen J.I.
A1 Stock, Norbert
A1 Emmerling, Franziska
A1 Demel, Jan
A1 Wright, Paul A.
A1 Demadis, Konstantinos D.
A1 Vassaki, Maria
A1 Costantino, Ferdinando
A1 Vivani, Riccardo
A1 Sallard, Sébastien
A1 Salcedo, Inés R.
A1 Cabeza-Díaz, Aurelio
A1 Taddei, Marco
K1 Fósforo - Compuestos
K1 Fosfatos
K1 Pilas de combustible
K1 Baterías de estado sólido
K1 Conductividad eléctrica
AB In September 2018, the First EuropeanWorkshop on Metal Phosphonates Chemistry broughttogether some prominent researchers in the field of metal phosphonates and phosphinates with theaim of discussing past and current research e orts and identifying future directions. The scope ofthis perspective article is to provide a critical overview of the topics discussed during the workshop,which are divided into two main areas: synthesis and characterisation, and applications. In terms ofsynthetic methods, there has been a push towards cleaner and more e cient approaches. This has ledto the introduction of high-throughput synthesis and mechanochemical synthesis. The recent successof metal–organic frameworks has also promoted renewed interest in the synthesis of porous metalphosphonates and phosphinates. Regarding characterisation, the main advances are the developmentof electron di raction as a tool for crystal structure determination and the deployment of in situcharacterisation techniques, which have allowed for a better understanding of reaction pathways.In terms of applications, metal phosphonates have been found to be suitable materials for severalpurposes: they have been employed as heterogeneous catalysts for the synthesis of fine chemicals, assolid sorbents for gas separation, notably CO2 capture, as materials for electrochemical devices, suchas fuel cells and rechargeable batteries, and as matrices for drug delivery.
PB MDPI    www.mdpi.com/journal/crystals
YR 2019
FD 2019-05-24
LK https://hdl.handle.net/10630/21005
UL https://hdl.handle.net/10630/21005
LA eng
NO Crystals 2019, 9, 270
DS RIUMA. Repositorio Institucional de la Universidad de Málaga
RD 20 ene 2026