RT Journal Article
T1 Valorization of furfural to obtain high value-sdded products with ZrO2- and Al2O3-Pillared clays
A1 Es Sih, Salima
A1 Franco-Duro, Francisco Ignacio
A1 García-Sancho, Cristina
A1 García-Mateos, Francisco José
A1 Rosas-Martínez, Juana María
A1 Moreno-Tost, Ramón
A1 Maireles-Torres, Pedro Jesús
A1 Cecilia-Buenestado, Juan Antonio
K1 Aldehídos - Reactividad
K1 Filosilicatos - Reactividad
AB Two phyllosilicates (montmorillonite and saponite) have been selected as starting materials to synthesize ZrO2- and Al2O3-pillared clays by the insertion of polyoxocations and subsequent calcination. These pillared clays display higher surface area, porosity and available acid sites in comparison to their respective raw clays. These samples were tested in the one-pot process to transform furfural into obtain valuable products. The incorporation of ZrO2 allows to reach the highest furfural conversion values, with high yields towards furfuryl alcohol (FOL) at shorter reaction times, whereas the formation of i-propyl furfuryl ether (iPFE) is favored at longer times, attaining iPFE yields of about 50% after 24 h at 170 ºC, using isopropanol as sacrificing alcohol.
PB Springer
YR 2024
FD 2024
LK https://hdl.handle.net/10630/31429
UL https://hdl.handle.net/10630/31429
LA eng
NO Es Sih, S., Franco-Duro, F., García-Sancho, C. et al. Valorization of Furfural to Obtain High Value-Added Products with ZrO2- and Al2O3-Pillared Clays. Top Catal (2024). https://doi.org/10.1007/s11244-024-01971-3
NO Funding for open access charge: Universidad de Málaga / CBUA
DS RIUMA. Repositorio Institucional de la Universidad de Málaga
RD 20 ene 2026