RT Conference Proceedings
T1 Triindoles as excellent platforms for organic semiconductors: from crystalline molecules to porous polymers
A1 Gámez-Valenzuela, Sergio
A1 Ponce-Ortiz, Rocío
A1 Ruiz-Delgado, María del Carmen
K1 Electrónica orgánica
K1 Porosidad
K1 Química física
K1 Polímeros conductores
K1 Conductores orgánicos
AB Organic semiconductors are one of the most promising candidates for next-generation electronics applications. In this sense, triindole-based systems have demonstrated great potential as p-type semiconductors in organic field-effect transistors (OFETs).1 In this project, a mixed experimental and theoretical study of three new crystalline N-trimethyltriindoles endowed with different functionalities at 3, 8 and 13 positions are investigated (Figure 1a), with the main goal of exploring the correlation between the electronic nature of the substituents and their solid-state organization and semiconductor behavior.2 On the other hand, the design and synthesis of covalent organic framework materials (constructed from the union of different covalently linked conjugated platforms) is being deeply investigated in organic electronic.3 Recently, in collaboration with the groups of Dr. Berta Gómez-Lor and Dr. Jose Ignacio Martínez, we have theoretically studied how the structural and the electronic properties of new porous triindole-based polymers (Figure 1b) can be modulated by the (i) modification of the linkage position from para (T2) to meta (T3), (ii) by the insertion of different π-bridges (phenylene or alkyne) between the cores and (iii) by the increment of the number of π-bridges from 3 to 6 units (T2,3).4
YR 2022
FD 2022
LK https://hdl.handle.net/10630/24177
UL https://hdl.handle.net/10630/24177
LA eng
NO Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech
DS RIUMA. Repositorio Institucional de la Universidad de Málaga
RD 22 ene 2026