RT Conference Proceedings
T1 Studying the electronic and charge transport properties of two cyclocarbazole derivates
A1 González-Núñez, Raúl
A1 Badía-Domínguez, María Irene
A1 Gámez-Valenzuela, Sergio
A1 Yang, Anna
A1 Moore, Jeffrey
A1 Huang, Feihe
A1 Hernández-Jolín, Víctor
A1 Ruiz-Delgado, María del Carmen
A1 Ponce-Ortiz, Rocío
K1 Semiconductores orgánicos
AB Molecular systems have proven to be efficient active materials in electronics, being possible alternatives to the inorganic semiconductors used nowadays in electronic devices. For this reason, organic electronics has emerged as a research field with great potential and interest. In this project, an experimental and theoretical study of two carbazole-based macrocycles is presented (Figure 1). Specifically, we investigated the impact of the inclusion of acetylene groups on the electronic and molecular structures of these macrocycles, as well as their potential as charge transporting materials. The first studied compound (Cz) is composed by four carbazole groups linked at their para position with respect to the nitrogen atom[1]. In the second compound (ACz), the carbazole units are connected through ethynylene groups[2]. For this study, Raman and UV-Vis absorption spectroscopies have been used in combination with theoretical calculations based on the density functional theory (DFT). In addition, the two studied compounds have been implemented in organic field-effect transistors (OFETs), to assess their potential as active materials in organic electronics. Overall, the inclusion of ethynylene groups as π-conjugated spacers is found to be a good strategy to improve the electronic delocalization in macrocycles.
YR 2022
FD 2022-06-30
LK https://hdl.handle.net/10630/24590
UL https://hdl.handle.net/10630/24590
LA eng
NO Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech.
DS RIUMA. Repositorio Institucional de la Universidad de Málaga
RD 20 ene 2026