RT Conference Proceedings
T1 Raman spectroscopy meets organic biradicals. Study of a new diindeno [B,I] anthracene derivative
A1 Casado-Cordón, Juan
A1 Zafra-Paredes, Jose Luis
K1 Efecto Raman de resonancia
AB In	recent	years,	there	has	been	a	renewed	interest	in	the	study	of	open-shell	polycyclic	aromatic hydrocarbons (PAHs). Among	 them,	 biradicals exhibit attractive	 electronic,	magnetic	 and	 optical	 properties	 which	 make	 them	 promising	 candidates	 for	 a	 wide	range	 of	 applications	 in	 organic	 electronics,	 such	 as	 nonlinear	 optics,	 molecular	spintronics,	 energy	 storage	 and	 organic	 photovoltaic	 devices	 sensitized	 by	 singlet	fission.	Despite	all	 the	promising	properties	of	open-shell	PAHs,	a	common	drawback	still	 needs	 to	 be	 overcome:	 the	 high	 reactivity	 of	 radicals,	 which	 implies	 that	 most	open-shell	 species	 tend	 to	 be	 too	 short-lived	 for	 practical	 aplications	 and	 even	 for	characterization [1].	In	this	regard,	Raman	spectroscopy	has	shown	to	be	a	suitable	tool	for	studying	this	kind	of	molecular	systems,	being	able	to	provide	valuable	information.This	 work reports the	 study	 of	 a	 new	 biradical,	 diindeno[b,i]anthracene	 (DIAn)[2],	 [3],	highlighting	 the	crucial	 role	played	by	Raman	Spectroscopy	in	 the	characterization	of	the	ground	electronic	state	as	well	as	in	the	rationalization	of	the	ambipolar	behavior	shown	in	OFETs.	To	this	end,	neutral	and	charged	species	has	been	studied	by	Raman	spectroscopy	as	a	function	of	excitation	wavelength,	temperatura and	pressure.
YR 2017
FD 2017
LK http://hdl.handle.net/10630/14187
UL http://hdl.handle.net/10630/14187
LA eng
NO Comunicación oral a congreso
NO Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech.
DS RIUMA. Repositorio Institucional de la Universidad de Málaga
RD 21 ene 2026