RT Conference Proceedings
T1 Preparation and characterization of phosphorus-containing electrocatalyst for OER, HER and ORR.
A1 Vílchez-Cózar, Álvaro
A1 Bazaga-García, Montse
A1 Olivera-Pastor, Pascual
A1 Cabeza-Díaz, Aurelio
A1 Pérez-Colodrero, Rosario Mercedes
K1 Catalizadores de metales de transición
AB Phosphorus-based materials, such as transition metal phosphides and phosphates/pyrophosphates, have drawn considerable attention as promising alternatives to noble metal-based catalysts (Pt, Ru, Ir) owing to their widely tunable electrocatalytic properties.In this work, we propose the preparation of electrocatalysts using metal phosphonates of composition M(O3PCH(OH)COOH)·2H2O (M2+= Mn, Fe, Co, and Ni) as precursors. The electrocatalysts were obtained by pyrolytic treatments (N2 or 5%H2-Ar atmospheres) giving rise to a wide family of crystalline and amorphous metal pyrophosphates and phosphides. The full-characterised solids by XRD (laboratory and synchrotron), TEM and XPS were then assayed as catalysts for Oxygen Evolution Reaction (OER), Oxygen Reduction Reaction (ORR) and Hydrogen Evolution Reaction (HER). The amorphous iron(II)-doped cobalt pyrophosphate and crystalline phosphides (MP and/or M2P; and M2+= Co, Ni) exhibited the best performances and long-times stabilities. On the other hand, pair distribution function (PDF) studies, using synchrotron radiation, and XPS analysis reveal that the amorphous/crystalline phases are stable for the HER and ORR processes, while solids evolve to other active phases, such as (oxy)hydroxides, upon conducting the OER. The performance of selected electrocatalysts has been tested for H2 production and monitored by laboratory X-ray computed nanotomography (nanoCT).
YR 2022
FD 2022-11
LK https://hdl.handle.net/10630/25580
UL https://hdl.handle.net/10630/25580
LA eng
NO Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech.
DS RIUMA. Repositorio Institucional de la Universidad de Málaga
RD 27 feb 2026