RT Journal Article T1 Integration of SuperCam based chemical imaging and clustering to correlate geochemistry and mineralogy in heterogeneous samples A1 García-Gómez, Laura A1 Población, Iraxte A1 Delgado-Pérez, Tomás A1 Laserna-Vázquez, José Javier A1 Velasquez, Marizu A1 Porizka, Pavel A1 Buday, Jakub A1 Kaiser, Josef A1 Lobato, Álvaro A1 Casado, Ana I. A1 Taravillo, Mercedes A1 Madariaga, Juan Manuel A1 Aramendia, Julene A1 Rull, Fernando A1 Carrizo, Daniel A1 Martínez-Frías, Jesús A1 Vadillo-Pérez, Iñaki A1 Vadillo-Pérez, José Miguel A1 Fortes-Román, Francisco Javier A1 Cabalín-Robles, Luisa María K1 Espectroscopía de plasma inducido por láser K1 Algoritmos computacionales K1 Aprendizaje automático (Inteligencia artificial) K1 Planetas - Exploración AB Peridotites are ultramafic rocks whose mineralogical diversity makes them suitable case studies for testing analytical methodologies. In this study, a peridotite sample from the Ronda massif (Málaga, Spain) was examined demonstrating a practical methodology for distinguishing geochemically distinct regions within complex lithologies. The sample was analyzed using a multi-instrumental approach combining laser-induced breakdown spectroscopy (LIBS), micro-energy dispersive X-ray fluorescence (µ-EDXRF), and Raman spectroscopy, all of them integrated in the Perseverance rover payload. LIBS and µ-EDXRF were used to assess elemental composition and spatial distribution across the sample, whereas Raman spectroscopy confirmed the presence of mineral phases such as, olivine, pyroxenes, and chromiferous spinels in specific regions. Elemental LIBS ratios such as Mg# and Cr# further supported the identification of compositional variations related to mineral phases. Spectral LIBS data were processed using k-means clustering to segment geochemical zones and detect spatial trends. This integrated spectroscopic and statistical approach enables interpretation of ultramafic rock complexity and offers an efficient framework for planetary exploration under mission constraints. PB Nature YR 2025 FD 2025-10-29 LK https://hdl.handle.net/10630/40598 UL https://hdl.handle.net/10630/40598 LA eng NO García-Gómez, L., Población, I., Delgado, T. et al. Integration of SuperCam based chemical imaging and clustering to correlate geochemistry and mineralogy in heterogeneous samples. Sci Rep 15, 37808 (2025). https://doi.org/10.1038/s41598-025-21770-4 DS RIUMA. Repositorio Institucional de la Universidad de Málaga RD 20 ene 2026