RT Journal Article
T1 Combined Operando XANES and NMR and ESR Spectroscopies for the Determination of VPO Dynamic States.
A1 Guerrero-Pérez, María Olga
A1 Lapina, Olga B.
A1 Rasmussen, Soren B.
A1 Bañares, Miguel Ángel
K1 Catalizadores de vanadio
K1 Espectroscopía
AB Nanoscaled-VPO (vanadium phosphate oxide) catalysts have been prepared on an alumina support with the objective of obtaining crystallites of the active phase with a high surface-to-volume ratio. Since the catalysed reaction occurs at the surface, these nanoscaled catalysts allows studying surface species transformations with a minimized signal from the bulk dominion. The chemical environment and oxidation state of these species has been determined by a combination of NMR, ESR and XANES spectroscopies. The results have allowed to optimize V + P coverage and V/P molar ratio to minimize the concentration of isolated vanadium oxide species and maximize V4+ concentration. The distribution of phosphorus islands ordered and significantly distorted of tetra- and penta-coordinated aluminium sites of the catalytic support, thus shaping the catalytic material to an optimal structure for the desired partial oxidation reaction.
PB Springer
YR 2023
FD 2023-05-29
LK https://hdl.handle.net/10630/30363
UL https://hdl.handle.net/10630/30363
LA eng
NO Guerrero-Pérez, M.O., Lapina, O.B., Rasmussen, S.B. et al. Combined Operando XANES and NMR and ESR Spectroscopies for the Determination of VPO Dynamic States. Top Catal 66, 1161–1170 (2023). https://doi.org/10.1007/s11244-023-01827-2
DS RIUMA. Repositorio Institucional de la Universidad de Málaga
RD 22 ene 2026