RT Journal Article
T1 Cation template assisted oligoethylene glycol desymmetrization by intramolecular Cannizzaro reaction of topologically remote aldehydes.
A1 Ruiz-Sanchez, Antonio Jesus
A1 Vida-Pol, Yolanda
A1 Suau Suárez, Rafael
A1 Pérez-de-Inestrosa-Villatoro, Ezequiel
K1 Aldehídos
AB Oligoethylene glycol chains containing 2–5 ethylene glycol units, and possessing a benzyl alcohol and a benzoic acid end groups, can be quantitatively obtained by intramolecular Cannizzaro reaction of the corresponding remote benzaldehyde end groups. The process is quite effective if a complex with an appropriate cation is formed to allow the two aldehyde groups to be spatially confined near enough each other for the intramolecular redox process.
PB Elsevier
YR 2008
FD 2008
LK https://hdl.handle.net/10630/33122
UL https://hdl.handle.net/10630/33122
LA eng
NO Política de acceso abierto tomada de: https://v2.sherpa.ac.uk/id/publication/15869
DS RIUMA. Repositorio Institucional de la Universidad de Málaga
RD 20 ene 2026