RT Conference Proceedings
T1 Formation of stimuli-responsive cyclophanes by self-assembly: the case of carbazole-based biradicals
A1 Ruiz-Delgado, María del Carmen
A1 Badía-Domínguez, María Irene
A1 Hernández-Jolín, Víctor
A1 Hartl, Frantisek
A1 Hongxiang, Li
A1 Sancho-García, Juan C.
A1 Pérez Guardiola, Andrés
A1 Rodríguez-González, Sandra
K1 Ciclofanos
AB Dynamic covalent bonds has recently received lot of attention because of their unique feature to become reversible under mild conditions.[1] In this context, π-conjugated biradical compounds has emerged as essential building blocks.[2] For instance, we have demonstrated that 2,7-dicyanomethylene-9-(2-ethylhexyl)carbazole biradical reversibly converts to a macrocycle cyclophane upon soft stimuli (temperature, pressure, light), showing strong chromic effects.[3] We now extent this study towards longer conjugated carbazole backbone (i.e., indolocarbazole shown in Figure 1), aiming at investigating how the elongation of the conjugated backbone impacts on the formation of stimuli-responsive cyclophanes. The self-assembly process is investigated both in solution and solid state by linking theory and experiments.
YR 2019
FD 2019-01-16
LK https://hdl.handle.net/10630/17149
UL https://hdl.handle.net/10630/17149
LA eng
NO Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech.
DS RIUMA. Repositorio Institucional de la Universidad de Málaga
RD 13 abr 2026