RT Journal Article
T1 Acyclic Aldehydo Sugars: 1,3-dimethyl-4,5-diamino Uracil as Recoverable Carbonyl Protecting Group
A1 Fuentes-Ríos, David
A1 Doña-Flores, Manuel
A1 López-Romero, Juan Manuel
A1 Rico, Rodrigo
K1 Química orgánica
K1 Azúcar - Aspectos moleculares
AB 1,3-dimethyl-4,5-diaminouracil has been used as an efficient protecting group for the car-bonyl moiety in sugars by the formation of the imine group. The protection reaction is carried out undermild conditions, the yields are quantitative in most of the cases, and the protecting group is completelyrecovered and reused. After per-acetylation, deprotection is accomplished at room temperature withaqueous formic acid to produce acyclic acetylated sugars in good global yield.
PB Bentham Science
YR 2024
FD 2024
LK https://hdl.handle.net/10630/40542
UL https://hdl.handle.net/10630/40542
LA eng
NO Letters in Organic Chemistry, 2024, 21, 213-215
DS RIUMA. Repositorio Institucional de la Universidad de Málaga
RD 20 ene 2026