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oai:riuma.uma.es:10630/141102026-02-03T12:28:28Zcom_10630_2254col_10630_37959

Tuning Proton Conductivity Properties of Lanthanide Amino-Sulfophosphonates-Loaded Nafion Composite Membranes Bazaga-García, Montse Salcedo, Inés R. Pérez-Colodrero, Rosario Mercedes Villemin, Didier Cabeza-Díaz, Aurelio Olivera-Pastor, Pascual Losilla, Enrique R. Del Río, Carmen López González, María del Mar Electrolitos - Conductividad Polímeros PEMFCs Metal sulfophosphonates Polymer membranes Nafion Proton conductivity Crystal structure Polymer-based electrolytes in proton exchange membrane fuel cells (PEMFCs) utilize acidic groups as proton carriers and hydrogen bonding networks as proton-conducting pathways to facilitate proton transport. Crystalline acid-functionalized metal phosphonates are potential proton conductors while maintaining a high hydration degree below 100 °C. This property may be combined with Nafion-like polymers which tend to dehydrate at the operating conditions of PEMFCs [1,2]. In this work, preliminary results of the preparation of lanthanide amino-sulfophosphonates-loaded Nafion composites membranes and the corresponding electrical properties are reported. Synthesis conditions of lanthanide derivatives were optimized following a hightrough-put screening at 140 °C. Their crystal structures, solved from synchrotron X-ray powder diffraction data, corresponds to layered frameworks where the acidic groups, -CPO3H or -SO3H, point toward the interlamellar region interacting by H-bond with the lattice water. The composites were prepared by mixing the metal phosphonates with Nafion solution at different loadings. The membranes were characterized by SEM, XRD and FT-IR. A study of the proton conductivity as a function of the composite membranes was carried out at 90 °C and 95% RH. Referencias [1] Y. Gao, R. Broersen, W. Hageman, N. Yan, M. C. Mittelmeijer-Hazeleger, G. Rothenberg, S. Tanase. J. Mater. Chem. A, 2015, 3, 22347–22352. [2] A. Cabeza, P. Olivera-Pastor, R. M. P. Colodrero. Tailored Organic-Inorganic Materials, Brunet, E., Colón, J.L., Clearfield, A., Eds.; John Wiley & Sons, Inc. 2015; Ch. 4, 137−191. Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech. 2017-07-05T09:51:10Z 2017-07-05T09:51:10Z 2017-07-05 2017-07-05 conference output http://hdl.handle.net/10630/14110 eng XXXVI REUNIÓN BIENAL DE LA REAL SOCIEDAD ESPAÑOLA DE QUÍMICA Sitges, España 25/06/2017 - 29/06/2017 by-nc-nd open access application/pdf