2026-05-30T07:31:19Zhttps://riuma.uma.es/rest/oai/request

oai:riuma.uma.es:10630/141542026-02-03T12:16:21Zcom_10630_2254col_10630_37959

Thiophene-bridged bis-naphthalimidic structures (even and odd) with n-type and ambipolar ofets applications López Espejo, Guzmán Espectroscopía Raman Tiofeno A brand new series of thiophene bridged bis-naphthalimides has been obtained. These molecules can act as semiconductors and have an even or an odd number of thiophene rings, so that they vary their molecular dipole moments, which have some influence in their molecular packing. With theoretical calculations, the stability of their derivative -dimers (either parallel or antiparallel) has been elucidated. Results indicate a face-to-face parallel molecular packing for these semiconductors, regardless of their estimated molecular dipole moments. The results obtained are reasonable regarding the field-effect mobilities that have been measured in a bottom-gate topcontact transistor architecture; no direct correlation between performances and dipolar moments is shown. Ambipolar field-effect mobilities have been recorded for the systems of greatest length (2NDI-4T and 2NDI-5T). 2017-07-07T10:52:14Z 2017-07-07T10:52:14Z 2017 2017-07-07 conference output http://hdl.handle.net/10630/14154 eng Bienal de Química de la RSEQ Sitges, Barcelona 25 de junio de 2017 open access by-nc-nd