2026-05-31T02:10:00Zhttps://riuma.uma.es/rest/oai/request

oai:riuma.uma.es:10630/144972026-02-03T12:08:10Zcom_10630_2254col_10630_37959

00925njm 22002777a 4500 dc Cárdenas Valdivia, Abel author Vereda-Alonso, Elisa Isabel author López-Guerrero, María del Mar author García-de-Torres, Amparo author Cano-Pavón, José Manuel author 2017-09-21 A green and rapid method was developed for the simultaneous separation/preconcentration and sequential monitoring pf arsenic, antimony and mercury by flow injection magnetic solid phase extraction coupled with on-line chemical vapor generation and determination by high resolution continuum source graphite furnace atomic absorption spectrometry. The system is based on chelating/cationic retention of the analytes onto a magnet based reactor designed to contain functionalized magnetic nanoparticles (MNPs). The MNP score allows overcoming the back-pressure problems that usually happen in SPME methods with NPs thanks to the possibility of inmobilizing the MNPs by applying an external magnetic field. Several chemical and flow variables were considered as factors in the optimization process using central composite designs. With the optimized procedure the detection limits obtained were 0.2, 0.003 and 0.4 µg/L for As, Sb and Hg respectively. For the quality control of the analytical performance and the validation of the developed method the analysis of two certified samples TM 24.3 and TMDA 54.4 Fortified Lake Waters was addressed. The results showed good agreement with the certified values. http://hdl.handle.net/10630/14497 Química analítica Sequential determination of traces of As, Sb and hg by on-line magnetic solid phase extraction coupled with Hr-Cs-Cvg-Gfaas