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oai:riuma.uma.es:10630/170882026-02-03T11:59:23Zcom_10630_2254col_10630_37959

00925njm 22002777a 4500 dc Ruiz-Delgado, María del Carmen author 2018-12-18 Pi-conjugated biradical compounds become essential building blocks in DCC (dynamic covalent chemistry).1 This field is based on the creation of structural scaffolds based on chemical components which interact through strong but reversible bonds. Importantly, dynamic covalent bonds will be at the center of attention because of their unique feature to become reversible under mild conditions.2 Recently, we have demonstrated the reversible interconversion between a stable quinoid precursor based on a para-substituted carbazole with terminal dicyanomethylene groups and a macrocycle cyclophane upon soft external stimuli (temperature, pressure, light), which results on strong chromic features.3 In this work, we investigate the impact of the substitution pattern (i.e., the insertion of dicyanomethylene groups at the 2,7 (para) or 3,6 (meta) positions or the elongation of the carbazole backbone) on the formation of stimuli-responsive cyclophanes by self-assembly. To this end, we use a combined experimental and theoretical study that links vibrational spectroscopy (Raman and IR) with DFT calculations. https://hdl.handle.net/10630/17088 Resistencia de materiales Carbazole-based biradicaloids as potential building blocks for dynamic covalent chemistry