2026-06-01T10:18:54Zhttps://riuma.uma.es/rest/oai/requestoai:riuma.uma.es:10630/171492026-02-03T12:27:36Zcom_10630_2254col_10630_37959
RIUMA. Repositorio Institucional de la Universidad de Málaga
author
Ruiz-Delgado, María del Carmen
author
Badía-Domínguez, María Irene
author
Hernández-Jolín, Víctor
author
Hartl, Frantisek
author
Hongxiang, Li
author
Sancho-García, Juan C.
author
Pérez Guardiola, Andrés
author
Rodríguez-González, Sandra
2019-01-16T10:59:53Z
2019-01-16T10:59:53Z
2019-01-16
https://hdl.handle.net/10630/17149
Dynamic covalent bonds has recently received lot of attention because of their unique feature to become reversible under mild conditions.[1] In this context, π-conjugated biradical compounds has emerged as essential building blocks.[2] For instance, we have demonstrated that 2,7-dicyanomethylene-9-(2-ethylhexyl)carbazole biradical reversibly converts to a macrocycle cyclophane upon soft stimuli (temperature, pressure, light), showing strong chromic effects.[3] We now extent this study towards longer conjugated carbazole backbone (i.e., indolocarbazole shown in Figure 1), aiming at investigating how the elongation of the conjugated backbone impacts on the formation of stimuli-responsive cyclophanes. The self-assembly process is investigated both in solution and solid state by linking theory and experiments.
eng
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Ciclofanos
Formation of stimuli-responsive cyclophanes by self-assembly: the case of carbazole-based biradicals
conference output
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URL
https://riuma.uma.es/bitstreams/e49d4fd3-62a9-422c-8e6b-963e492852da/download
File
MD5
ed4ae0f0696368ed849ac5113c409689
292623
application/pdf
Abstrac_Ruiz Delgado.pdf