2026-05-30T08:10:02Zhttps://riuma.uma.es/rest/oai/requestoai:riuma.uma.es:10630/228802026-02-03T11:53:24Zcom_10630_2254col_10630_37959
RIUMA. Repositorio Institucional de la Universidad de Málaga
author
Cuesta-García, Ana María
author
Morales-Cantero, Alejandro
author
Gómez-de-la-Torre, María de los Ángeles
author
Santacruz-Cruz, María Isabel
author
García-Aranda, Miguel Ángel
2021-09-24T07:24:57Z
2021-09-24T07:24:57Z
2021
https://hdl.handle.net/10630/22880
Portland cement (PC) is the most manufactured product in the world. However, cement industry is one of the major contributors for greenhouse gas emissions. For every ton of grey PC clinker, around 0.87 CO2 tons are released into the atmosphere. For this reason, alternative cements having similar performances to ordinary PC are needed. A recent work [1] has identified the use of supplementary cementitious materials (SCMs) as the most favourable approach for lowering CO2 emissions in the cement industry. The hydration reactions of tricalcium silicate, Ca3SiO5 (main phase of PC) consist of its dissolution, the precipitation of the nanocrystalline C-S-H gel, jointly with the formation of portlandite, Ca(OH)2 according to equation (1). C-S-H gel was described to be composed by defective nanocrystalline clinotobermorite, amorphous Ca(OH)2 and gel pore water [2]. The calcium hydroxide formed in reaction (1) can be employed to yield additional secondary C-(A)-S-H through the pozzolanic reaction with SCMs.
Ca3SiO5 + 5.2H2O→1.2Ca(OH)2 +1/9[Ca11Si9O28(OH)2.8.5H2O] // 0.58[Ca(OH)2] // 2.37H2O (1)
Crystalline C-S-H gel –nanocrystalline // amorphous .
The analysis of nanocrystalline/amorphous phases in cement matrices which contain high amounts of crystalline phases is very challenging. Pair distribution function (PDF) in combination with synchrotron radiation is key to characterize cement pastes. This work focuses on the characterization of amorphous and nanocrystalline phases which are present in cement related pastes by total scattering PDF. We have studied a series of tricalcium silicate pastes blended with silica fume hydrated at four months and dicalcium silicate pastes hydrated at longer ages [3]. PDF data were collected at ALBA Synchrotron, beamline MSPD, see Figure 1.
spa
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Nanotecnología - Congresos
Cemento - Industria
Pair distribution function as a tool to characterize C-S-H gels
conference output
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URL
https://riuma.uma.es/bitstreams/7e8e73a4-4f01-4e68-b9e6-2983695216e7/download
File
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4785f34e25c0199edf2fad88d2b1ac2b
709239
application/pdf
Toscaland_Abstract_Template_PDF_Cuesta.pdf