2026-05-28T16:10:15Zhttps://riuma.uma.es/rest/oai/request

oai:riuma.uma.es:10630/236112026-02-03T11:16:58Zcom_10630_2254col_10630_37953

Error analysis and correction for quantitative phase analysis based on Rietveld-internal method: Whether the minor phases can be ignored? Zhao, Piqi Lu, Lingchao Liu, Xianping Gómez-de-la-Torre, María de los Ángeles Xin, Cheng Cemento Escoria The Rietveld-internal standard method for Bragg-Brentano reflection geometry (q/2q) X-ray diffraction (XRD) patterns is implemented to determine the amorphous phase content. The effect of some minor phases on quantitative accuracy is assessed. The numerical simulation analysis of errors and the related corrections are discussed. The results reveal that high purity of crystalline phases in the standard must be strictly ensured. The minor amorphous or non-quantified crystalline phases exert significant effect on the quantitative accuracy, even with less than 2 wt% if ignored. The error levels are evaluated by numerical simulation analysis and the corresponding error-accepted zone is suggested. To eliminate such error, a corrected equation is proposed. When the adding standard happens to be present in sample, it should be also carefully dealt with even in low amounts. Based on that ignorance, the absolute and relative error equations (DAE, DRE) are derived, as proposed. The conditions for high quantitative accuracy of original equation is strictly satisfied with a lower amount of standard phase present in sample, less than 2 wt%, and a higher dosage of internal standard, larger than 20 wt%. The corrected equation to eliminate such quantitative error is suggested. 2022-01-13T13:54:38Z 2022-01-13T13:54:38Z 2022-01-13T13:54:38Z 2018-02 journal article Zhao, P.; Lu, L.; Liu, X.; De la Torre, A.G.; Cheng, X. Error Analysis and Correction for Quantitative Phase Analysis Based on Rietveld-Internal Standard Method: Whether the Minor Phases Can Be Ignored? Crystals 2018, 8, 110. https://doi.org/10.3390/cryst8030110 https://hdl.handle.net/10630/23611 https://doi.org/10.3390/cryst8030110 eng http://creativecommons.org/licenses/by-nc-nd/4.0/ open access Attribution-NonCommercial-NoDerivatives 4.0 Internacional MDPI