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Morales-Benítez, Irene Montoro-Leal, Pablo García-Mesa, Juan Carlos López-Guerrero, María del Mar Vereda-Alonso, Elisa Isabel 2023-04-19T10:22:36Z 2023-04-19T10:22:36Z 2023 Morales-Benítez, Montoro-Leal, P., García-Mesa, J. C., López Guerrero, M. M., & Vereda Alonso, E. (2023). New magnetic chelating sorbent for chromium speciation by magnetic solid phase extraction on-line with inductively coupled plasma optical emission spectrometry. Talanta (Oxford), 256, 124262–. https://doi.org/10.1016/j.talanta.2023.124262 https://hdl.handle.net/10630/26291 https://doi.org/10.1016/j.talanta.2023.124262 A novel sorbent material employing magnetic nanoparticles (MNPs) coupled to graphene oxide (GO) functionalized with 4-aminobenzenesulfonic acid (M@GO-ABS) has been synthesized and applied to develop an inexpensive and automatic method for Cr(III) and Cr(VI) speciation in environmental samples; the developed method combines inductively coupled plasma optical emission spectrometry (ICP-OES) with on-line magnetic solid phase extraction (MSPE). Two magnetic-knotted reactors containing M@GO-ABS were installed in the eight-port injection valve of a flow injection (FI) manifold. Two different eluents were used, one for Cr(VI) (the most toxic chromium species) and one for total Cr concentration. Cr(III) concentration was calculated by the difference between Cr(VI) concentration and total Cr concentration. The optimized method presented detection limits (LOD, peak height) of 0.1 μg L eng http://creativecommons.org/licenses/by-nc-nd/4.0/ open access Attribution-NonCommercial-NoDerivatives 4.0 Internacional Sólidos -- Propiedades magnéticas New magnetic chelating sorbent for chromium speciation by magnetic solid phase extraction on-line with inductively coupled plasma optical emission spectrometry journal article