2026-06-02T02:05:20Zhttps://riuma.uma.es/rest/oai/requestoai:riuma.uma.es:10630/283122026-02-03T11:19:03Zcom_10630_2254col_10630_37953
RIUMA. Repositorio Institucional de la Universidad de Málaga
author
Shirani, Shiva
author
Cuesta-García, Ana María
author
Gómez-de-la-Torre, María de los Ángeles
author
Santacruz-Cruz, María Isabel
author
Koufany, Imane
author
Redondo-Soto, Cinthya
author
Salcedo, Inés R.
author
León-Reina, Laura
author
García-Aranda, Miguel Ángel
2023-12-15T10:41:01Z
2023-12-15T10:41:01Z
2023-11-14
S. Shirani, A. Cuesta, A.G. De la Torre, I. Santacruz, A. Morales-Cantero, I. Koufany, C. Redondo-Soto, I.R. Salcedo, L. León-Reina, M.A.G. Aranda, Mix and measure - Combining in situ X-ray powder diffraction and microtomography for accurate hydrating cement studies, Cement and Concrete Research, Volume 175, 2024, 107370, ISSN 0008-8846, https://doi.org/10.1016/j.cemconres.2023.107370
https://hdl.handle.net/10630/28312
10.1016/j.cemconres.2023.107370
It is reported an innovative methodology based on in situ MoKα1 laboratory X-ray powder diffraction (LXRPD)
and microtomography (μCT) avoiding any sample conditioning. The pastes are injected in 2.0 mm capillaries and
the extremes are just sealed. The measurements take place in the same region of the hydrating paste. Thick
capillaries are key to avoiding self-desiccation, which dictates the need of high-energy X-ray radiation for the
diffraction study. This approach has been tested with a PC 42.5 R paste having w/c = 0.50. μCT data were
collected at 12 h and 1, 3, 7 and 79 days. LXRPD data were acquired at 1, 3, 7 and 77 days. In this proof-ofprinciple
research, the same paste was also cured ex situ. Portlandite contents obtained by thermal analysis,
ex situ powder diffraction, in situ mass balance calculation and in situ powder diffraction were 13.8, 13.1, 13.1
and 12.5 wt%, respectively. From the μCT study, the grey value histogram evolution with time showed a crossing
point which allowed us to distinguish (appearing) hydrated products from (dissolving) unhydrated cement
particles. Segmentations were carried out by global thresholding and the random forest approach (one type of
supervised Machine Learning). The comparison of the segmented results for the unhydrated cement fraction and
the Rietveld quantitative phase analysis outputs gave an agreement of 2 %. The potential of this methodology to
deal with more complex binders is also presented.
eng
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Cemento Portland
Rayos X - Difracción
Sistemas de imágenes
Mix and measure - Combining in situ X-ray powder diffraction and microtomography for accurate hydrating cement studies.
journal article
CjEuIEFjZXB0YW5kbyBlc3RhIGxpY2VuY2lhLCB1c3RlZCAoZWwgYXV0b3IvZXMgbyBlbCBwcm9waWV0YXJpby9zIGRlIGxvcyBkZXJlY2hvcyBkZSBhdXRvcikgZ2FyYW50aXphIGEgbGEgVW5pdmVyc2lkYWQgZGUgTcOhbGFnYSBlbCBkZXJlY2hvIG5vIGV4Y2x1c2l2byBkZSBhcmNoaXZhciwgcmVwcm9kdWNpciwgY29udmVydGlyIChjb21vIHNlIGRlZmluZSBtw6FzIGFiYWpvKSwgY29tdW5pY2FyIHkvbyBkaXN0cmlidWlyIHN1IGRvY3VtZW50byBtdW5kaWFsbWVudGUgZW4gZm9ybWF0byBlbGVjdHLDs25pY28uCgoyLiBUYW1iacOpbiBlc3TDoSBkZSBhY3VlcmRvIGNvbiBxdWUgbGEgVW5pdmVyc2lkYWQgZGUgTcOhbGFnYSBwdWVkYSBjb25zZXJ2YXIgbcOhcyBkZSB1bmEgY29waWEgZGUgZXN0ZSBkb2N1bWVudG8geSwgc2luIGFsdGVyYXIgc3UgY29udGVuaWRvLCBjb252ZXJ0aXJsbyBhIGN1YWxxdWllciBmb3JtYXRvIGRlIGZpY2hlcm8sIG1lZGlvIG8gc29wb3J0ZSwgcGFyYSBwcm9ww7NzaXRvcyBkZSBzZWd1cmlkYWQsIHByZXNlcnZhY2nDs24geSBhY2Nlc28uCgozLiBEZWNsYXJhIHF1ZSBlbCBkb2N1bWVudG8gZXMgdW4gdHJhYmFqbyBvcmlnaW5hbCBzdXlvIHkvbyBxdWUgdGllbmUgZWwgZGVyZWNobyBwYXJhIG90b3JnYXIgbG9zIGRlcmVjaG9zIGNvbnRlbmlkb3MgZW4gZXN0YSBsaWNlbmNpYS4gVGFtYmnDqW4gZGVjbGFyYSBxdWUgc3UgZG9jdW1lbnRvIG5vIGluZnJpbmdlLCBlbiB0YW50byBlbiBjdWFudG8gbGUgc2VhIHBvc2libGUgc2FiZXIsIGxvcyBkZXJlY2hvcyBkZSBhdXRvciBkZSBuaW5ndW5hIG90cmEgcGVyc29uYSBvIGVudGlkYWQuCgo0LiBTaSBlbCBkb2N1bWVudG8gY29udGllbmUgbWF0ZXJpYWxlcyBkZSBsb3MgY3VhbGVzIG5vIHRpZW5lIGxvcyBkZXJlY2hvcyBkZSBhdXRvciwgZGVjbGFyYSBxdWUgaGEgb2J0ZW5pZG8gZWwgcGVybWlzbyBzaW4gcmVzdHJpY2Npw7NuIGRlbCBwcm9waWV0YXJpbyBkZSBsb3MgZGVyZWNob3MgZGUgYXV0b3IgcGFyYSBvdG9yZ2FyIGEgbGEgVW5pdmVyc2lkYWQgZGUgTcOhbGFnYSBsb3MgZGVyZWNob3MgcmVxdWVyaWRvcyBwb3IgZXN0YSBsaWNlbmNpYSwgeSBxdWUgZXNlIG1hdGVyaWFsIGN1eW9zIGRlcmVjaG9zIHNvbiBkZSB0ZXJjZXJvcyBlc3TDoSBjbGFyYW1lbnRlIGlkZW50aWZpY2FkbyB5IHJlY29ub2NpZG8gZW4gZWwgdGV4dG8gbyBjb250ZW5pZG8gZGVsIGRvY3VtZW50byBlbnRyZWdhZG8uCgo1LiBTaSBlbCBkb2N1bWVudG8gc2UgYmFzYSBlbiB1bmEgb2JyYSBxdWUgaGEgc2lkbyBwYXRyb2NpbmFkYSBvIGFwb3lhZGEgcG9yIHVuYSBhZ2VuY2lhIHUgb3JnYW5pemFjacOzbiBkaWZlcmVudGUgZGUgbGEgVW5pdmVyc2lkYWQgZGUgTcOhbGFnYSwgc2UgcHJlc3Vwb25lIHF1ZSBzZSBoYSBjdW1wbGlkbyBjb24gY3VhbHF1aWVyIGRlcmVjaG8gZGUgcmV2aXNpw7NuIHUgb3RyYXMgb2JsaWdhY2lvbmVzIHJlcXVlcmlkYXMgcG9yIGVzdGUgY29udHJhdG8gbyBhY3VlcmRvLgoKNi4gTGEgVW5pdmVyc2lkYWQgZGUgTcOhbGFnYSBpZGVudGlmaWNhcsOhIGNsYXJhbWVudGUgc3UvcyBub21icmUvcyBjb21vIGVsL2xvcyBhdXRvci9lcyBvIHByb3BpZXRhcmlvL3MgZGUgbG9zIGRlcmVjaG9zIGRlbCBkb2N1bWVudG8sIHkgbm8gaGFyw6EgbmluZ3VuYSBhbHRlcmFjacOzbiBkZSBzdSBkb2N1bWVudG8gZGlmZXJlbnRlIGEgbGFzIHBlcm1pdGlkYXMgZW4gZXN0YSBsaWNlbmNpYS4KCg==
URL
https://riuma.uma.es/bitstreams/e1b3b135-20e0-4e04-b18b-ddcb596a978a/download
File
MD5
17aea0514b8d588b59d34ff99d7b8b45
2252156
application/pdf
CEMCON-D-23-00844-R2_marked.pdf