2026-05-28T08:00:26Zhttps://riuma.uma.es/rest/oai/request

oai:riuma.uma.es:10630/283122026-02-03T11:19:03Zcom_10630_2254col_10630_37953

Mix and measure - Combining in situ X-ray powder diffraction and microtomography for accurate hydrating cement studies. Shirani, Shiva Cuesta-García, Ana María Gómez-de-la-Torre, María de los Ángeles Santacruz-Cruz, María Isabel Koufany, Imane Redondo-Soto, Cinthya Salcedo, Inés R. León-Reina, Laura García-Aranda, Miguel Ángel Cemento Portland Rayos X - Difracción Sistemas de imágenes It is reported an innovative methodology based on in situ MoKα1 laboratory X-ray powder diffraction (LXRPD) and microtomography (μCT) avoiding any sample conditioning. The pastes are injected in 2.0 mm capillaries and the extremes are just sealed. The measurements take place in the same region of the hydrating paste. Thick capillaries are key to avoiding self-desiccation, which dictates the need of high-energy X-ray radiation for the diffraction study. This approach has been tested with a PC 42.5 R paste having w/c = 0.50. μCT data were collected at 12 h and 1, 3, 7 and 79 days. LXRPD data were acquired at 1, 3, 7 and 77 days. In this proof-ofprinciple research, the same paste was also cured ex situ. Portlandite contents obtained by thermal analysis, ex situ powder diffraction, in situ mass balance calculation and in situ powder diffraction were 13.8, 13.1, 13.1 and 12.5 wt%, respectively. From the μCT study, the grey value histogram evolution with time showed a crossing point which allowed us to distinguish (appearing) hydrated products from (dissolving) unhydrated cement particles. Segmentations were carried out by global thresholding and the random forest approach (one type of supervised Machine Learning). The comparison of the segmented results for the unhydrated cement fraction and the Rietveld quantitative phase analysis outputs gave an agreement of 2 %. The potential of this methodology to deal with more complex binders is also presented. 2023-12-15T10:41:01Z 2023-12-15T10:41:01Z 2023-12-15T10:41:01Z 2023-11-14 journal article S. Shirani, A. Cuesta, A.G. De la Torre, I. Santacruz, A. Morales-Cantero, I. Koufany, C. Redondo-Soto, I.R. Salcedo, L. León-Reina, M.A.G. Aranda, Mix and measure - Combining in situ X-ray powder diffraction and microtomography for accurate hydrating cement studies, Cement and Concrete Research, Volume 175, 2024, 107370, ISSN 0008-8846, https://doi.org/10.1016/j.cemconres.2023.107370 https://hdl.handle.net/10630/28312 10.1016/j.cemconres.2023.107370 eng http://creativecommons.org/licenses/by-nc-nd/4.0/ open access Attribution-NonCommercial-NoDerivatives 4.0 Internacional Elsevier