2026-06-05T12:26:31Zhttps://riuma.uma.es/rest/oai/requestoai:riuma.uma.es:10630/302352026-02-03T10:49:49Zcom_10630_2254col_10630_37953
RIUMA. Repositorio Institucional de la Universidad de Málaga
author
Mendez-Gil, Nayara
author
Gámez-Valenzuela, Sergio
author
Echeverri, Marcelo
author
Suyo, Gary H.
author
Ruiz-Delgado, María del Carmen
author
Gómez-Lor, Berta
2024-02-09T08:29:15Z
2024-02-09T08:29:15Z
2024-02-08
N. Méndez-Gil, S. Gámez-Valenzuela, M. Echeverri, G. H. Suyo, M. Iglesias, M. C. R. Delgado, B. Gómez-Lor, Donor-Acceptor Truxene-Based Porous Polymers: Synthesis, Optoelectronic Characterization and Defense-Related Applications. Adv. Funct. Mater. 2024, 2316754. https://doi.org/10.1002/adfm.202316754
https://hdl.handle.net/10630/30235
10.1002/adfm.202316754
Four donor-acceptor (D-A) polymers are synthesized by combining two different electron donors (truxene and its more electron rich triaza analogue, triindole) with an electron-deficient monomer (benzothiadiazole) through two different positions (2,7,13 or 3,8,13) and their optoelectronic properties are studied by theoretical and experimental methods. One of the polymers exhibits remarkable sensing capabilities for explosive nitraoaromatics while another demonstrated efficient photocatalytic activity in the aerobic sulfoxidation of the sulfur mustard simulant 2-chloro-ethyl ethyl sulfide (MGS) sulfoxidation. These results highlight their potential applications in defense-related areas. Moreover, the structure-performance relationships observed among the four polymers have enabled us to deepen the understanding of the mechanisms underlying the performance of these polymers in the aforementioned applications, thereby providing valuable insights to further improve their properties.
eng
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Química física
Polímeros
Polímeros conductores
Polímeros - Propiedades eléctricas
Industria militar
Donor-acceptor truxene-based porous polymers: synthesis, optoelectronic characterization and defense-related applications
journal article
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URL
https://riuma.uma.es/bitstreams/06a52c38-052f-42c6-b1b8-7a0f66e1d2a4/download
File
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35f1d88ca833bbe41b65fab72323bede
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application/pdf
Adv Funct Materials - 2024 - Méndez‐Gil - Donor‐Acceptor Truxene‐Based Porous Polymers Synthesis Optoelectronic.pdf