2026-05-31T11:28:22Zhttps://riuma.uma.es/rest/oai/requestoai:riuma.uma.es:10630/403022026-02-03T11:05:35Zcom_10630_2254col_10630_37953
RIUMA. Repositorio Institucional de la Universidad de Málaga
author
García-Gómez, Laura
author
Soriano, J.K.
author
Vadillo-Pérez, José Miguel
author
Ikeda, Y.
2025-10-17T11:19:34Z
2025-10-17T11:19:34Z
2026
L. García-Gómez, J.K. Soriano, J.M. Vadillo, Y. Ikeda, Improved detection capabilities of molecular emission in microwave-enhanced laser-induced plasma, Spectrochimica Acta Part B: Atomic Spectroscopy, Volume 235, 2026, 107356
https://hdl.handle.net/10630/40302
10.1016/j.sab.2025.107356
The detection of molecular emissions in laser-induced breakdown spectroscopy (LIBS) remains a subject of active research, driven by the need to improve both signal-to-noise ratios and spectral definition. Various enhancement strategies have been proposed, including double-pulse configurations and hybrid systems combining LIBS with complementary techniques like Raman spectroscopy or laser-induced fluorescence. While effective, these methods often introduce considerable experimental complexity. In this context, the present study explores microwave re-excitation (MW-LIBS) as a more accessible alternative capable of modifying plasma dynamics without additional optical alignment. The introduction of microwave energy increases collisional activity within the plasma, extending its duration to the millisecond range and amplifying emission signals. Molecular species were monitored under this regime, focusing on canonical emitters such as CN and CaO, as well as less commonly reported systems like SnO, which has not been previously described in LIBS literature. The most significant enhancements were observed under conditions approaching the plasma ablation threshold. Moreover, MW-LIBS enabled the observation of molecular emissions in the red and near-infrared regions, which are generally limited in conventional LIBS due to detector inefficiencies and reduced plasma radiative output. These findings provide new insights into the mechanisms of molecular formation in sustained plasmas and demonstrate the potential of MW-LIBS for enhancing molecular diagnostics.
eng
Atribución 4.0 Internacional
Espectroscopía de plasma inducido por láser
Láseres en física
Química analítica
Improved detection capabilities of molecular emission in microwave-enhanced laser-induced plasma
journal article
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