2026-05-30T07:32:02Zhttps://riuma.uma.es/rest/oai/requestoai:riuma.uma.es:10630/404242026-02-03T11:09:48Zcom_10630_2254col_10630_37953
RIUMA. Repositorio Institucional de la Universidad de Málaga
author
Medina Ruíz, M Esther
author
Maderuelo-Solera, Rocío
author
Jiménez-Gómez, Carmen Pilar
author
Moreno-Tost, Ramón
author
Malpartida-García, Irene
author
García-Sancho, Cristina
author
Cecilia-Buenestado, Juan Antonio
author
Len, Christophe
author
Maireles-Torres, Pedro Jesús
2025-10-23T10:16:41Z
2025-10-23T10:16:41Z
2024-09-25
ACS Sustainable Chem. Eng. 2024, 12, 14910−14920
https://hdl.handle.net/10630/40424
10.1021/acssuschemeng.4c06333
A series of Pd-based catalysts supported on oxides with different acid−base properties has been prepared,
characterized, and used for the valorization of furfural into value-added chemicals, with polymethylhydroxysiloxane (PMHS) as a reducing agent being an alternative to the use of hydrogen gas and alcohols as hydrogen donors. PMHS is a polymeric waste product of the silicone industry and is also recognized as a sustainable reductant for epoxide hydrosilylations and diastereoselective radical reduction in organic chemistry. Moreover, it is nontoxic, water/air insensitive, and soluble in most organic solvents due to its low viscosity. So, PMHS has been employed for the reduction of furfural in the presence of supported Pd catalysts. Although all catalysts tested are catalytically active, those supported on Al2O3 and SiO2 showed complete conversion after 30 min of reaction at 303 K, whereas 27.7% was attained using MgO as support.
eng
Catálisis heterogénea
Biomasa
Ingeniería química
Supported Palladium Catalysts for the Selective Hydrogenation of Furfural with Polymethylhydrosiloxane.
journal article
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URL
https://riuma.uma.es/bitstreams/c7d31226-b30f-425d-9fad-983c7118f194/download
File
MD5
1a8b56d5e690c92a2ebeeb64af792259
1131930
application/pdf
Furfural hydrogenation PMHS Pd_v_8_01_2024.pdf