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Listar por autor "Choquesillo-Lazarte, Duane"
Mostrando ítems 1-15 de 15
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Common Structural Features in Calcium Hydroxyphosphonoacetates. A High-Throughput Screening
Pérez-Colodrero, Rosario Mercedes; Cabeza-Díaz, Aurelio
; Olivera-Pastor, Pascual
; Papadaki, M.; Rius, Jordi; Choquesillo-Lazarte, Duane; García-Ruíz, Juan M.; Demadis, Konstantinos D.; García-Aranda, Miguel Ángel
[et al.] (2011-03-11)
R,S-Hydroxyphosphonoacetic acid (H3HPA) is an inexpensive multidentate organic ligand widely used for the preparation of organo-inorganic hybrid materials. There are reports of several crystal structures and the variability ... -
Crystal engineering in confined spaces. A novel method to grow crystalline metal phosphonates in alginate gel systems
Stavgianoudaki, Nikoleta; Papathanasiou, Konstantinos E.; Pérez-Colodrero, Rosario Mercedes; Choquesillo-Lazarte, Duane; García-Ruíz, Juan M.; Cabeza-Díaz, Aurelio
; García-Aranda, Miguel Ángel
; Demadis, Konstantinos D.[et al.] (The Royal Society of Chemistry, 2012)
In this paper we report a crystal growth method for metal phosphonate frameworks in alginate gels. It consists of a metalcontaining alginate gel, in which a solution of phosphonate ligand is slowly diffused. Crystals of ... -
Divalent Metal Vinylphosphonate Layered Materials: Compositional Variability, Structural Peculiarities, Dehydration Behavior, and Photoluminescent Properties
Pérez-Colodrero, Rosario Mercedes; Cabeza-Díaz, Aurelio
; Olivera-Pastor, Pascual
; Choquesillo-Lazarte, Duane; García-Ruíz, Juan M.; Turner, Adele; Ilia, Gheorghe; Maranescu, Bianca; Papathanasiou, Konstantinos E.; Hix, Gary B.; Demadis, Konstantinos D.; García-Aranda, Miguel Ángel
[et al.] (American Chemical Society, 2011-09-27)
A family of M-VP (M = Ni, Co, Cd, Mn, Zn, Fe, Cu, Pb; VP = vinylphosphonate) and M-PVP (M = Co, Cd; PVP = phenylvinylphosphonate) materials have been synthesized by hydrothermal methods and characterized by FTIR, elemental ... -
Exploiting the Multifunctionality of M2+/Imidazole−Etidronates for Proton Conductivity (Zn2+) and Electrocatalysis (Co2+, Ni2+) toward the HER, OER, and ORR
Vílchez-Cózar, Álvaro; Armakola, Eirini; Gjika, Maria; Visa, Aurelia; Bazaga-García, Montse; Olivera-Pastor, Pascual; Choquesillo-Lazarte, Duane; Marrero-López, David
; Cabeza-Díaz, Aurelio
; Pérez-Colodrero, Rosario Mercedes
; Demadis, Konstantinos D.[et al.] (American Chemical Society, 2022-02-22)
This work deals with the synthesis and characterization of one-dimensional (1D) imidazole-containing etidronates, [M2(ETID)(Im)3]·nH2O (M = Co2+ and Ni2+; n = 0, 1, 3) and Zn2(ETID)2(H2O)2](Im)2, as well as the corresponding ... -
Guest Molecule-Responsive Functional Calcium Phosphonate Frameworks for Tuned Proton Conductivity
Bazaga-García, Montse; Pérez-Colodrero, Rosario Mercedes; Papadaki, M.; Garczarek, Piotr; Zon, Jerzy; Olivera-Pastor, Pascual
; Losilla, Enrique R.; León-Reina, Laura; García-Aranda, Miguel Ángel
; Choquesillo-Lazarte, Duane; Demadis, Konstantinos D.; Cabeza-Díaz, Aurelio
[et al.] (American Chemical Society, 2014-03-18)
We report the synthesis, structural characterization, and functionality of an open-framework hybrid that combines Ca2+ ions and the rigid polyfunctional ligand 5-(dihydroxyphosphoryl) isophthalic acid (PiPhtA). Ca-PiPhtA-I ... -
Imidazole-containing Co2+ and Ni2+ etidronates: crystal structures and electrochemical behaviour
Bazaga-García, Montse; Pérez-Colodrero, Rosario Mercedes; Vílchez-Cózar, Álvaro; Armakola, Eirini; Gjika, M.; Visa, Aurelia; Choquesillo-Lazarte, Duane; Olivera-Pastor, Pascual
; Cabeza-Díaz, Aurelio
; Demadis, Konstantinos D.[et al.] (2021)
Metal phosphonates-based coordination polymers (CPs) are known to exhibit versatile structural diversity and functionality. Thus, they have been used, among other applications, as electrocatalyst precursors for both, PEMFCs ... -
Luminescent and Proton Conducting Lanthanide Coordination Networks Based On a Zwitterionic Tripodal Triphosphonate
Bazaga-García, Montse; Angeli, Giasemi K.; Papathanasiou, Konstantinos E.; Salcedo, Inés R.; Olivera-Pastor, Pascual; Losilla, Enrique R.; Choquesillo-Lazarte, Duane; Hix, Gary B.; Cabeza-Díaz, Aurelio
; Demadis, Konstantinos D.[et al.] (American Chemical Society, 2016-07-14)
The synthesis, structural characterization, luminescence properties, and proton conduction performance of a new family of isostructural cationic 2D layered compounds are reported. These have the general formula ... -
Multifunctional Luminescent and Proton-Conducting Lanthanide Carboxyphosphonate Open-Framework Hybrids Exhibiting Crystalline-to-Amorphous-to-Crystalline Transformations
Pérez-Colodrero, Rosario Mercedes; Papathanasiou, Konstantinos E.; Stavgianoudaki, Nikoleta; Olivera-Pastor, Pascual
; Losilla, Enrique R.; García-Aranda, Miguel Ángel
; León-Reina, Laura; Sanz, Jesús; Sobrados, Isabel; Choquesillo-Lazarte, Duane; García-Ruíz, Juan M.; Atienzar, Pedro; Rey, Fernando; Demadis, Konstantinos D.; Cabeza-Díaz, Aurelio
[et al.] (American Chemical Society, 2012-09-15)
The chemistry of metal phosphonates has been progressing fast with the addition of new materials that possess novel structural features and new properties, occasionally in a cooperative manner. In this paper, we report a ... -
Phase Transformation Dynamics in Sulfate-Loaded Lanthanide Triphosphonates. Proton Conductivity and Application as Fillers in PEMFCs
Salcedo, Inés R.; Pérez-Colodrero, Rosario Mercedes; Bazaga-García, Montse; López González, María del Mar; Del Río, Carmen; Xanthopoulos, Konstantinos; Demadis, Konstantinos D.; Hix, Gary B.; Furasova, Aleksandra D.; Choquesillo-Lazarte, Duane; Olivera-Pastor, Pascual
; Cabeza-Díaz, Aurelio
[et al.] (ACS Publications. American Chemical Society, 2021)
Phase transformation dynamics and proton conduction properties are reported for cationic layer-featured coordination polymers derived from the combination of lanthanide ions (Ln3+) with nitrilo-tris(methylenephosphonic ... -
Proton conductivity and luminiscence properties of lanthanide aminotriphosphonates
Bazaga-García, Montse; Angeli, Giasemi K.; Papathanasiou, Konstantinos E.; Salcedo, Inés R.; Olivera-Pastor, Pascual; Losilla, Enrique R.; Choquesillo-Lazarte, Duane; Hix, Gary B.; Cabeza-Díaz, Aurelio
; Demadis, Konstantinos D.[et al.] (2016)
Metal phosphonates are multifunctional solids with tunable properties, such as internal H-bond networks, and high chemical and thermal stability [1]. In the present work, we describe the synthesis, structural characterization, ... -
Proton Conductivity in Sulfate-Containing Lanthanide Nitrilotris-methylphosphonates
Salcedo, Inés R.; Cabeza-Díaz, Aurelio; Bazaga-García, Montse; Pérez-Colodrero, Rosario Mercedes
; Choquesillo-Lazarte, Duane; Hix, Gary B.; Ramírez-Losilla, Enrique
; Olivera-Pastor, Pascual
[et al.] (2019-09-12)
Multifunctional metal phosphonates are coordination polymers (CPs) whose structures are usually composed of extended hydrogen-bond networks and thus making them potential candidates as proton conductors [1]. Moreover, these ... -
Synthesis and structural characterization of 2-D layered copper(II) styrylphosphonate coordination polymers
Maranescu, Bianca; Visa, Aurelia; Ilia, Gheorghe; Simon, Zeno; Demadis, Konstantinos D.; Pérez-Colodrero, Rosario Mercedes; Cabeza-Díaz, Aurelio
; Vallcorba, Oriol; Rius, Jordi; Choquesillo-Lazarte, Duane[et al.] (Taylor & Francis, 2014-04-11)
We report the synthesis, physicochemical characterization, and crystal structure of Cu-SP (SP = styrylphosphonic acid, H2O3PCH=CH2(C6H5)), the first reported example of a metal derivative of SP. The starting SP acid was ... -
Three-Component Copper-Phosphonate-Auxiliary Ligand Systems: Proton Conductors and Efficient Catalysts in Mild Oxidative Functionalization of Cycloalkanes
Armakola, Eirini; Pérez-Colodrero, Rosario Mercedes; Bazaga-García, Montse; Salcedo, Inés R.; Choquesillo-Lazarte, Duane; Cabeza-Díaz, Aurelio
; Kirillova, Marina V.; Kirillov, Alexander M.; Demadis, Konstantinos D.[et al.] (ACS publications, 2018-08-13)
The synthesis, structural characterization, topological analysis, proton conductivity, and catalytic properties are reported of two Cu(II)-based compounds, namely a dinuclear Cu(II) complex [Cu2(μ-VPA)2(phen)2(H2O)2]· 8H2O ... -
Tuning Proton Conductivity in A Multifunctional Calcium Phosphonate Hybrid Framework
Cabeza-Díaz, Aurelio; Bazaga-García, Montse; Pérez-Colodrero, Rosario Mercedes
; Papadaki, M.; Olivera-Pastor, Pascual
; Losilla, Enrique R.; León-Reina, Laura; Choquesillo-Lazarte, Duane; Garczarek, Piotr; Zon, Jerzy; García-Aranda, Miguel Ángel
; Demadis, Konstantinos D.[et al.] (2014-06-25)
Multi-chelating phosphonate ligands are organic linkers alternative to polycarboxylates and other ligands providing synthetic access to a number of thermally- and chemically-stable MOFs [1]. Metal phosphonates are amenable ... -
Tuning Proton Conductivity in Alkali Metal Phosphonocarboxylates by Cation Size-Induced and Water-Facilitated Proton Transfer Pathways
Bazaga-García, Montse; Papadaki, M.; Pérez-Colodrero, Rosario Mercedes; Olivera-Pastor, Pascual
; Losilla, Enrique R.; Nieto-Ortega, Belén; García-Aranda, Miguel Ángel
; Choquesillo-Lazarte, Duane; Cabeza-Díaz, Aurelio
; Demadis, Konstantinos D.[et al.] (American Chemical Society, 2014-12-20)
The structural and functional chemistry of a family of alkali-metal ions with racemic R,S-hydroxyphosphonoacetate (M-HPAA; M = Li, Na, K, Cs) are reported. Crystal structures were determined by X-ray data (Li+, powder ...