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Mostrando ítems 1-11 de 11
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Assessment of ATR-FTIR spectroscopy with multivariate analysis to investigate the binding mechanisms of Ag and TiO2 nanoparticles to Chelex®-100 or Metsorb™ for the DGT technique
Pouran, Hamid; Pérez-Colodrero, Rosario Mercedes; Wu, Shuang; Hix, Gary B.; Zakharova, Julia; Zhang, Hao[et al.] (The Royal Society of Chemistry, 2020-01-09)Studying nanomaterials' ecotoxicology is not new but there are still gaps in our understanding of their fate in the environment. A major challenge is lack of reliable tools to measure available concentrations of nanoparticles ... -
Divalent Metal Vinylphosphonate Layered Materials: Compositional Variability, Structural Peculiarities, Dehydration Behavior, and Photoluminescent Properties
Pérez-Colodrero, Rosario Mercedes; Cabeza-Díaz, Aurelio; Olivera-Pastor, Pascual; Choquesillo-Lazarte, Duane; García-Ruíz, Juan M.; Turner, Adele; Ilia, Gheorghe; Maranescu, Bianca; Papathanasiou, Konstantinos E.; Hix, Gary B.; Demadis, Konstantinos D.; García-Aranda, Miguel Ángel[et al.] (American Chemical Society, 2011-09-27)A family of M-VP (M = Ni, Co, Cd, Mn, Zn, Fe, Cu, Pb; VP = vinylphosphonate) and M-PVP (M = Co, Cd; PVP = phenylvinylphosphonate) materials have been synthesized by hydrothermal methods and characterized by FTIR, elemental ... -
Luminescent and Proton Conducting Lanthanide Coordination Networks Based On a Zwitterionic Tripodal Triphosphonate
Bazaga-García, Montse; Angeli, Giasemi K.; Papathanasiou, Konstantinos E.; Salcedo, Inés R.; Olivera-Pastor, Pascual; Losilla, Enrique R.; Choquesillo-Lazarte, Duane; Hix, Gary B.; Cabeza-Díaz, Aurelio; Demadis, Konstantinos D.[et al.] (American Chemical Society, 2016-07-14)The synthesis, structural characterization, luminescence properties, and proton conduction performance of a new family of isostructural cationic 2D layered compounds are reported. These have the general formula ... -
Materials chemistry: design and synthesis of luminescent and biologically active materials
Hix, Gary B. (2018-10-02)The need to synthesise new materials is driven by the need for materials with specific properties. Those properties are determined by the final application. In this talk we will explore the design of materials which are ... -
Materials chemistry: Design, Synthesis and Functionality
Hix, Gary B. (2017-09-28)The need to synthesise new materials is driven by the need for materials with specific functionality, which is in turn driven by the intended final application. In this talk we will explore the design of materials based ... -
Phase Transformation Dynamics in Sulfate-Loaded Lanthanide Triphosphonates. Proton Conductivity and Application as Fillers in PEMFCs
Salcedo, Inés R.; Pérez-Colodrero, Rosario Mercedes; Bazaga-García, Montse; López González, María del Mar; Del Río, Carmen; Xanthopoulos, Konstantinos; Demadis, Konstantinos D.; Hix, Gary B.; Furasova, Aleksandra D.; Choquesillo-Lazarte, Duane; Olivera-Pastor, Pascual; Cabeza-Díaz, Aurelio[et al.] (ACS Publications. American Chemical Society, 2021)Phase transformation dynamics and proton conduction properties are reported for cationic layer-featured coordination polymers derived from the combination of lanthanide ions (Ln3+) with nitrilo-tris(methylenephosphonic ... -
Proton conductivity and luminiscence properties of lanthanide aminotriphosphonates
Bazaga-García, Montse; Angeli, Giasemi K.; Papathanasiou, Konstantinos E.; Salcedo, Inés R.; Olivera-Pastor, Pascual; Losilla, Enrique R.; Choquesillo-Lazarte, Duane; Hix, Gary B.; Cabeza-Díaz, Aurelio; Demadis, Konstantinos D.[et al.] (2016)Metal phosphonates are multifunctional solids with tunable properties, such as internal H-bond networks, and high chemical and thermal stability [1]. In the present work, we describe the synthesis, structural characterization, ... -
Proton Conductivity in Sulfate-Containing Lanthanide Nitrilotris-methylphosphonates
Salcedo, Inés R.; Cabeza-Díaz, Aurelio; Bazaga-García, Montse; Pérez-Colodrero, Rosario Mercedes; Choquesillo-Lazarte, Duane; Hix, Gary B.; Ramírez-Losilla, Enrique; Olivera-Pastor, Pascual[et al.] (2019-09-12)Multifunctional metal phosphonates are coordination polymers (CPs) whose structures are usually composed of extended hydrogen-bond networks and thus making them potential candidates as proton conductors [1]. Moreover, these ... -
Structural Variability in Multifunctional Metal Xylenediaminetetraphosphonate Hybrids
Pérez-Colodrero, Rosario Mercedes; Angeli, Giasemi K.; Bazaga-García, Montse; Olivera-Pastor, Pascual; Villemin, Didier; Losilla, Enrique R.; Martos, Estefanía Q.; Hix, Gary B.; García-Aranda, Miguel Ángel; Demadis, Konstantinos D.; Cabeza-Díaz, Aurelio[et al.] (American Chemical Society, 2013-07-24)Two new families of divalent metal hybrid derivatives from the aromatic tetraphosphonic acids 1,4- and 1,3-bis(aminomethyl)benzene-N,N′-bis(methylenephosphonic acid), (H2O3PCH2)2−N−CH2C6H4CH2−N(CH2PO3H2)2 (designated herein ... -
Synthesis and antibacterial activity of bimetallic carboxyphosphonates
Cabeza-Díaz, Aurelio; Pérez-Colodrero, Rosario Mercedes; Vílchez-Cózar, Álvaro; Olivera-Pastor, Pascual; Hix, Gary B.; Bazaga-García, Montse[et al.] (2023)As a class of coordination polymers (CPs), metal phosphonates (MPs) are constructed by coordination bonds connecting metal sites and phosphonate (RPO3 2−) ligands, where the metal sites are dispersed uniformly at the atomic ... -
Tunable crystal structure and proton conductivity of lanthanide nitrilotrismethylphosphonates
Salcedo, Inés R.; Pérez-Colodrero, Rosario Mercedes; Hix, Gary B.; Cabeza-Díaz, Aurelio; Bazaga-García, Montse; Ramírez-Losilla, Enrique; Olivera-Pastor, Pascual[et al.] (2018-10-01)Metal phosphonates are multifunctional solids with remarkable stability and proton conducting properties owing to their structure is usually composed of extended hydrogen-bond networks that favor proton transfer pathways ...