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Listar por autor "Ramírez-Losilla, Enrique"
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A novel multilaminated composite cathode for solid oxide fuel cells.
Dos-Santos-Gómez, Lucía; Porras-Vázquez, José Manuel; Martín, Francisco; Ramos-Barrado, José Ramón; Ramírez-Losilla, Enrique; Marrero-López, David[et al.] (Elsevier, 2019-05-28)A novel electrode architecture consisting in alternating layers of La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF) and Ce0.9Gd0.1O1.95 (CGO) is prepared for the first time by spray-pyrolysis deposition and investigated as cathode material ... -
A review on recent advances and trends in symmetrical electrodes for solid oxide cells.
Zamudio-García, Javier; Caizán-Juanarena, Leire; Porras-Vázquez, José Manuel; Ramírez-Losilla, Enrique; Marrero-López, David (Elsevier, 2021-12-04)Symmetrical solid oxide cells (SSOCs) with identical air and fuel electrodes have gained significant scientific interest in the last decade because they offer several advantages over conventional cell configurations. ... -
Applications of N,N-bis(phosphonomethyl)glycine-derived Sn4+ or Co2+ phosphonates as proton conductors or energy-conversion electrocatalysts.
Cañamero-Cebrián, Fernando; Pérez-Colodrero, Rosario Mercedes; Vílchez-Cózar, Álvaro; Bazaga-García, Montse; Ramírez-Losilla, Enrique; Olivera-Pastor, Pascual; Cabeza-Díaz, Aurelio[et al.] (2023)Metal phosphonates (MPs), a subclass of coordination polymers, may exhibit acidic groups such as POH, SO3H, COOH, N+-H, etc. Combining these features with electrocatalytically active transition metals, make them highly ... -
Ce0.8Gd0.2O2‐δ / La0.6Sr0.4CoO3 Heterostructures prepared by pulsed laser deposition
Dos-Santos-Gómez, Lucía; Porras-Vázquez, José Manuel; Ramírez-Losilla, Enrique; Marrero-López, David (2018-09-14)Oxide interfaces have received greater attention due to the possibility to obtain properties that are very different from bulk materials. Due to the wide variety of electronic and ionic phenomena than can be detected at ... -
Compatibility and performance of SOFCs based on lanthanum tungstates
Dos-Santos-Gómez, Lucía; Porras-Vázquez, José Manuel; Zayas-Rey, María José; Ramírez-Losilla, Enrique; Marrero-López, David (2015-07-10)Rare-earth tungstates with general composition “Ln6WO12” have attracted great attention in last few years due to their relatively high mixed proton-electron conductivity [1, 2]. One of the main ad-vantages of these ... -
Cristaloquímica y Conductividad de ion óxido en Oxo-cuspidinas
Martín-Sedeño, María del Carmen (Universidad de Málaga, Servicio de Publicaciones, 2006)El trabajo de investigación se ha centrado en el estudio (preparación y caracterización estructural y eléctrica) de las oxo-cuspidinas con fórmula general A4(M2O71)O2 (A=La, Nd, Sm, Gd; M=Ga, Al) como posibles materiales ... -
Desarrollo y control microestructural en materiales para pilas de combustible de óxidos sólidos
Dos-Santos-Gómez, Lucía (UMA Editorial, 2018-10-17)Las pilas de combustible de óxidos sólidos (SOFCs) son una de las alternativas más prometedoras para producir energía eléctrica de manera eficiente y respetuosa con el medio ambiente. Durante la fabricación de una SOFC es ... -
Doping effects on the structure and electrical properties of La2Ce2O7 proton conductors.
Zamudio-García, Javier; Dos-Santos-Gómez, Lucía; Porras-Vázquez, José Manuel; Ramírez-Losilla, Enrique; Marrero-López, David (Elsevier, 2020-01-01)Recent studies have reported that the conductivity of La2Ce2O7 proton conductors is improved by aliovalent doping, despite the high concentration of oxygen vacancies in the pristine material. In this study, we provide ... -
Effect of calcium sulfate source on the hydration of calcium sulfoaluminate eco-cement
García-Maté, Marta; Gómez-de-la-Torre, María de los Ángeles; León-Reina, Laura; Ramírez-Losilla, Enrique; García-Aranda, Miguel Ángel; Santacruz-Cruz, María Isabel[et al.] (2014)The availability of cements, including eco-cements, with tailored mechanical properties is very important for special applications in the building industry. Here we report a full study of the hydration of calcium sulfoaluminate ... -
Efficient symmetrical electrodes based on LaCrO3 via microstructural engineering.
Zamudio-García, Javier; Porras-Vázquez, José Manuel; Ramírez-Losilla, Enrique; Marrero-López, David (Elsevier, 2021-09-30)Novel nanostructured electrodes, La0.98Cr0.75B0.25O3δ (B = Mn, Fe, Ti and Cu), are prepared by a single spraypyrolysis deposition method directly on the electrolyte and a porous Ce0.9Gd0.1O1.95 (CGO) scaffold. ... -
Enhancing the Electrochemical Performance in Symmetrical Solid Oxide Cells through Nanoengineered Redox-Stable Electrodes with Exsolved Nanoparticles
Zamudio-García, Javier; Porras-Vázquez, José Manuel; Ramírez-Losilla, Enrique; Marrero-López, David (American Chemical Society, 2023-12-25)Symmetrical solid oxide cells (SSOCs) have recently gained significant attention for their potential in energy conversion due to their simplified cell configuration, cost-effectiveness, and excellent reversibility. However, ... -
From light to heavy alkali metal tetraphosphonates (M = Li, Na, K, Rb, Cs): cation size-induced structural diversity and waterfacilitated proton conductivity
Salcedo, Inés R.; Pérez-Colodrero, Rosario Mercedes; Bazaga-García, Montse; Vasileiou, Antonia; Papadaki, Maria; Olivera-Pastor, Pascual; Infantes-Molina, Antonia; Ramírez-Losilla, Enrique; Mezei, Gellert; Cabeza-Díaz, Aurelio; Demadis, Konstantinos D.[et al.] (The Royal Society of Chemistry, 2018-09)A family of alkali metal-based frameworks containing the tetraphosphonate ligand hexamethylenediamine- N,N,N′,N′-tetrakisIJmethylenephosphonic acid), HDTMP, is reported. A cation size-induced structural diversity, from ... -
High efficiency cathodes for SOFCs prepared by spray-pyrolysis
Dos-Santos-Gómez, Lucía; Ramírez-Losilla, Enrique; Marrero-López, David (2015-07-10)In recent years, lowering the operating temper-ature of the Solid Oxide Fuel Cells (SOFCs) to the intermediate temperature range (500-700 ºC) has become the main challenge for this technology. The electrolyte resistance ... -
High-Throughput Synthesis of Pillared-Layered Magnesium Tetraphosphonate Coordination Polymers: Framework Interconversions and Proton Conductivity Studies
Pérez-Colodrero, Rosario Mercedes; Salcedo, Inés R.; Bazaga-García, Montse; Barouda, Eleni; Papadaki, Maria; Papathanasiou, Konstantinos E.; Hernández Alonso, Daniel; Rius, Jordi; García-Aranda, Miguel Ángel; Ramírez-Losilla, Enrique; Olivera-Pastor, Pascual; Demadis, Konstantinos D.; Cabeza-Díaz, Aurelio[et al.] (MDPI, www.mdpi.com/journal/inorganics, 2018-09-11)Novel pillared-layered framework materials were synthesized by high-throughput or microwave-assisted methodology that contain Mg2+ and the zwitterionic linker HDTMP (hexamethylenediamine-N,N,N0,N0-tetrakis(methylenephosphonic ... -
Highly oriented and fully dense CGO films prepared by spray-pyrolysis and different precursor salts.
Dos-Santos-Gómez, Lucía; Zamudio-García, Javier; Porras-Vázquez, José Manuel; Ramírez-Losilla, Enrique; Marrero-López, David (Elsevier, 2020-03-19)CeO2–based thin films are prepared by spray-pyrolysis deposition from different aqueous precursor solutions containing nitrate, chloride or acetate salts. The morphology and orientation growth strongly depends on the precursor ... -
Impact of the lanthanide size on the polymorphism and electrical properties of Ln5.4MoO11.1 (Ln = Nd, Sm and Gd)
Rubio-Vives, Rafael; Porras-Vázquez, José Manuel; Dos-Santos-Gómez, Lucía; Zamudio-García, Javier; Infantes-Molina, Antonia; Canales-Vázquez, J.; Marrero-López, David; Ramírez-Losilla, Enrique[et al.] (Elsevier, 2023)Mixed proton-electronic conductors are of great interest for high temperature electrochemical devices, such as hydrogen separation membranes. In this contribution, ceramics with composition Ln5.4MoO11.1 (Ln = Nd, Sm and ... -
In-situ early-age hydration study of sulfobelite cements by synchrotron powder diffraction
Álvarez-Pinazo, Gema; Cuesta-García, Ana María; García-Maté, Marta; Santacruz-Cruz, María Isabel; Ramírez-Losilla, Enrique; Sanfélix, Susana G.; Fauth, François[et al.] (Karen Scrivener, 2014)Eco-friendly belite calcium sulfoaluminate (BCSA) cement hydration behavior is not yet well understood. Here,we report an in-situ synchrotron X-ray powder diffraction study for the first hours of hydration of BCSA ... -
Influence of Bi1.5Y0.5O3 Active Layer on the Performance of Nanostructured La0.8Sr0.2MnO3 Cathode.
Zamudio-García, Javier; Albarrán-Aroca, Nerea; Porras-Vázquez, José Manuel; Ramírez-Losilla, Enrique; Marrero-López, David (MDPI, 2020-09-01)The efficiency of solid oxide fuel cell cathodes can be improved by microstructural optimization and using active layers, such as doped bismuth oxides. In this work, Bi1.5Y0.5O3 (BYO) films are prepared by spray-pyrolysis ... -
Influence of Nb-doping on the structural and electrical properties of lanthanum molybdates, La5.4MoO11.1
López Vergara, Adrián; Porras-Vázquez, José Manuel; Vollestad, Einar; Canales-Vázquez, J.; Ramírez-Losilla, Enrique; Marrero-López, David[et al.] (2018-06-28)Nowadays, hydrogen is receiving a great deal of attention as an energy carrier. Commonly, it is obtained by hydrocarbons reforming, such as natural gas, coal and biomass. However, the resulting hydrogen needs to be purified ...