Listar por autor "Nash, Rosie"
Mostrando ítems 1-3 de 3
-
Dicyanomethylene-substituted indolocarbazole diradicals: Investigating their challenging chemical reactivity and physical properties.
Badía-Domínguez, María Irene; Wang, Deliang; Nash, Rosie; Hernández-Jolín, Víctor
; Li, Hongxiang; Hartl, František; Ruiz-Delgado, María del Carmen[et al.] (2024)
π-Conjugated diradical compounds, with unpaired electrons in the ground state, are fundamentally important for understanding the nature of chemical bonds and have potential applications in material science[1]. It has been ... -
Dynamic Covalent Properties of a Novel Indolo[3,2-b]carbazole Diradical
Badía-Domínguez, Irene; Peña-Álvarez, Miriam; Wang, Deliang; Pérez Guardiola, Andrés; Vida-Pol, Yolanda; Rodríguez-González, Sandra; López Navarrete, Juan T.; Hernández-Jolín, Víctor; Sancho-García, Juan C.; García-Baonza, Valentín; Nash, Rosie; Hartl, František; Li, Hongxiang; Ruiz-Delgado, María del Carmen[et al.] (Wiley, 2021)
This work describes the synthesis and properties of a dicyanomethylene-substituted indolo[3,2-b]carbazole diradical ICz-CN. This quinoidal system dimerises almost completely to (ICz-CN)2, which contains two long C(sp3)−C(sp3) ... -
Tuneable stimuli-responsive behaviour, spectroscopic signatures and redox properties of indolo[3,2-b]carbazole-based diradicals
Badía-Domínguez, Irene; Wang, Deliang; Nash, Rosie; Hernández-Jolín, Víctor; Collison, David; Shanmugam, Muralidharan; Hongxiang, Li; Hartl, František; Ruiz-Delgado, María del Carmen[et al.] (RSC (Royal Society of Chemistry), 2024-09-07)
During the last decade, there has been an increasing interest in the rationalisation of how structural changes stabilise (or destabilise) diradical systems. Demonstrated herein is that indolocarbazole (ICz) diradicals, ...