Listar por autor "Porras-Vázquez, José Manuel"
Mostrando ítems 1-20 de 37
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Ajuste de las propiedades estructurales de molibdatos de lantano a través de la modificación de los entramados catiónicos y aniónicos
Porras-Vázquez, José Manuel
; Bergillos-Ruíz, Marta; López-Vergara, Adrián; Marrero-López, David; Losilla, Enrique R. (2018-06-28)
Los materiales basados en molibdatos de lantano, con fórmula general La6-xMoO12-, son candidatos a membranas de separación de hidrógeno debido su conductividad electrónica y protónica. Estos cristalizan en diferentes ... -
Boosting the Performance of La0.8Sr0.2MnO3-δ Electrodes by The Incorporation of Nanocomposite Active Layers
Zamudio-García, Javier; Caizán-Juanarena, Leire; Porras-Vázquez, José Manuel; Losilla, Enrique R.; Marrero-López, David (Wiley, 2022-07-07)
The use of active layers is a promising strategy to improve the properties of air electrodes for solid oxide fuel cells (SOFCs). In this work, La0.8Sr0.2MnO3-δ is combined with different oxide ion conductors Ce0.9Gd0.1O1.95, ... -
Ce0.8Gd0.2O2‐δ / La0.6Sr0.4CoO3 Heterostructures prepared by pulsed laser deposition
Dos-Santos-Gómez, Lucía; Porras-Vázquez, José Manuel; Ramírez-Losilla, Enrique; Marrero-López, David (2018-09-14)
Oxide interfaces have received greater attention due to the possibility to obtain properties that are very different from bulk materials. Due to the wide variety of electronic and ionic phenomena than can be detected at ... -
Compatibility and performance of SOFCs based on lanthanum tungstates
Dos-Santos-Gómez, Lucía; Porras-Vázquez, José Manuel; Zayas-Rey, María José; Ramírez-Losilla, Enrique; Marrero-López, David (2015-07-10)
Rare-earth tungstates with general composition “Ln6WO12” have attracted great attention in last few years due to their relatively high mixed proton-electron conductivity [1, 2]. One of the main ad-vantages of these ... -
Durability and performance of CGO barriers and LSCF cathode deposited by spray-pyrolysis
Dos-Santos-Gómez, Lucía; Hurtado, Javier; Porras-Vázquez, José Manuel; Losilla, Enrique R.; Marrero-López, David (Elsevier, 2018-03-19)
Ce0.9Gd0.1O1.95 (CGO) protective layers are prepared by two different methods to prevent the reaction between the Zr0.84Y0.16O1.92 (YSZ) electrolyte and the La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF) cathode. In the first method, ... -
Effect of preparation conditions on the polymorphism and transport properties of lanthanum molybdates
Porras-Vázquez, José Manuel; López-Vergara, Adrián; Infantes-Molina, Antonia; Canales-Vázquez, J.; Cabeza-Díaz, Aurelio; Losilla, Enrique R.; Marrero-López, David[et al.] (2017-10-24)
In this work, La6MoO12-based compounds were investigated as part of a new family of materials very competitive as hydrogen separation membranes [1,2]. La5.4MoO11.1 was synthesized by the freeze-drying precursor method and ... -
Effect of the modification of the cationic and anionic framework on the structural and electrical properties of lanthanum molybdates
López-Vergara, Adrián; Bergillos-Ruíz, Marta; Porras-Vázquez, José Manuel; Marrero-López, David; Losilla, Enrique R. (2019-07-19)
Fluorinated lanthanum molybdates have been prepared at 1500 and 1200 ºC for 1 h and cooled down at 5 ºC min-1. The combination of anionic (F-) and cationic (Nb5+) doping stabilizes the cubic polymorph without needing a ... -
Effect of Zn addition on the structure and electrochemical properties of codoped BaCe0.6Zr0.2Ln0.2O3-δ (Ln=Y, Gd, Yb) proton conductors
Zamudio-García, Javier; Porras-Vázquez, José Manuel; Dos-Santos-Gómez, Lucía; Losilla, Enrique R.; Marrero-López, David (Elsevier, 2018-05-02)
In this work, BaCe0.6Zr0.2Y0.2-xYbxO3-δ and BaCe0.6Zr0.2Gd0.2-xYbxO3-δ (x=0–0.20), proton conducting materials are prepared by the freeze-drying precursor method. The sintering conditions were optimized by adding ... -
Highly efficient La0.8Sr0.2MnO3-δ - Ce0.9Gd0.1O1.95 nanocomposite cathodes for solid oxide fuel cells
Dos-Santos-Gómez, Lucía; Zamudio-García, Javier; Porras-Vázquez, José Manuel; Losilla, Enrique R.; Marrero-López, David (Elsevier, 2017-12-15)
La0.8Sr0.2MnO3-δ-Ce0.9Gd0.1O1.95 (LSM-CGO) nanostructured cathodes are successfully prepared in a single process by a chemical spray-pyrolysis deposition method. The cathode is composed of nanometric particles of approximately ... -
Highly efficient LaCr0.75M0.25O3+δ (M= Ti, Mn, Fe, Co and Cu) nanostructured electrodes for Solid Oxide Fuel Cells
Zamudio-García, Javier; Porras-Vázquez, José Manuel; Losilla, Enrique R.; Marrero-López, David (2019-09-30)
Nanostructured composites electrodes based on lanthanum chromites has been prepared using Spray-pyrolysis precursor method achieving better Rp as SOFC electrodes. The performance in real SOFC is still in progress. -
Influence of lanthanum doping on the structure and transport properties of CeO2
Zamudio-García, Javier; Porras-Vázquez, José Manuel; Dos-Santos-Gómez, Lucía; Losilla, Enrique R.; Marrero-López, David (2019-06-10)
LaxCe1-xO2-x/2 materials are oxide and/or proton conductors depending on the La-content and they are of interest for numerous electrochemical applications at high temperatures, including membranes for hydrogen separation ... -
Influence of Nb-doping on the structural and electrical properties of lanthanum molybdates, La5.4MoO11.1
López-Vergara, Adrián; Porras-Vázquez, José Manuel; Vollestad, Einar; Canales-Vázquez, J.; Ramírez-Losilla, Enrique; Marrero-López, David[et al.] (2018-06-28)
Nowadays, hydrogen is receiving a great deal of attention as an energy carrier. Commonly, it is obtained by hydrocarbons reforming, such as natural gas, coal and biomass. However, the resulting hydrogen needs to be purified ... -
La0.8Sr0.2MnO3-d-based nanocomposite functional layers for improved cathode efficiency in SOFCs
Caizán-Juanarena, Leire; Zamudio-García, Javier; Porras-Vázquez, José Manuel; Ramírez-Losilla, Enrique; Marrero-López, David (2022)
Solid Oxide Fuel Cells (SOFC) are efficient electrochemical devices that are able to convert chemical energy in the form of fuels into electricity, but at low operating temperatures they are mainly limited by the high ... -
LaCr0.75Mn0.25O3+δ –CGO nanocomposite electrodes for highly efficient Solid Oxide Fuel Cells
Zamudio-García, Javier; Porras-Vázquez, José Manuel; Losilla, Enrique R.; Marrero-López, David (2021-07-24)
One of the most recent strategies to enhance the electrode performance is the preparation of nanocomposite materials, leading to an increase of the triple-phase-boundary (TPB) length. In this way, ... -
LaCrO3–CeO2-Based Nanocomposite Electrodes for Efficient Symmetrical Solid Oxide Fuel Cells
Zamudio-García, Javier; Porras-Vázquez, José Manuel; Ramírez-Losilla, Enrique; Marrero-López, David (2022-04-05)
La0.98Cr0.75Mn0.25O3−δ–Ce0.9Gd0.1O1.95 (LCM-CGO) nanocomposite layers with different LCM contents, between 40 and 60 wt %, are prepared in a single step by a spray-pyrolysis deposition method and evaluated as both air and ... -
Lanthanide molybdates, Ln5.4MoO11.1 (Ln = Nd, Sm and Gd), for hydrogen separation membranes
Porras-Vázquez, José Manuel; Zamudio-García, Javier; Marrero-López, David; Losilla, Enrique R. (Advanced Nano Materials, ANM2022, 2022-07-27)
Nowadays, lanthanide molybdates (Ln6-xMoO12-, Ln = La-Lu) are attracting attention as candidates for hydrogen separation membranes due to its high ambipolar proton-electron conductivity. In these compounds, a very high ... -
Lanthanum Molybdates: a comprehensive study for hydrogen separation membranes
(UMA Editorial, 2023)En esta Tesis doctoral, los materiales La6−xMoO12−δ (0 ≤ x ≤ 0.8) se investigan como una nueva familia de conductores cerámicos de protones. Se obtienen diferentes fases polimórficas con estructura romboédrica y cúbica, ... -
Metal carboxyphosphonates-based electrocatalysts
López-Vergara, Adrián; El-Refaei, S.M.; Russo, P.A.; Vilchez, A; Losilla, Enrique R.; Porras-Vázquez, José Manuel; Olivera-Pastor, Pascual; Pinna, N; Cabeza-Díaz, Aurelio[et al.] (2019-10-01)
Co1-xFex-HPAA metal phosphonates were prepared and pyrolyzed under N2 and H2/Ar flows. The resulting powders were structural and electrochemically characterized by XRD and CV, respectively. The obtained materials possess ... -
Modification of the Microstructure and Transport Properties of La2CuO4−δ Electrodes via Halogenation Routes
Dos-Santos-Gómez, Lucía; Zamudio-García, Javier; Porras-Vázquez, José Manuel; Ramírez-Losilla, Enrique; Marrero-López, David (IOAP-MPDI, 2022-06-16)
dos Santos-Gómez L, Zamudio-García J, Porras-Vázquez JM, R. Losilla E, Marrero-López D. Modification of the Microstructure and Transport Properties of La2CuO4−δ Electrodes via Halogenation Routes. Processes. 2022; 10(6):1206. ... -
Nanocrystalline cathodes for PC-SOFCs based on BCZY
Dos-Santos-Gómez, Lucía; Zea-Garcia, Jesus D.; Porras-Vázquez, José Manuel; Marrero-López, David; Ramírez-Losilla, Enrique (2016-09-27)
Perovskites based on BaCeO3-δ exhibit the highest proton conductivity among this class of materials, however, they are susceptible to hydration and carbonation in presence of water vapor and CO2 [1]. In contrast, the ...