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Listar por autor "Salcedo, Inés R."
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Accuracy in Cement Hydration Investigations: Combined X-ray Microtomography and Powder Diffraction Analyses
Salcedo, Inés R.; Cuesta-Garcia, Ana Maria; Shirani, Shiva; León-Reina, Laura; García-Aranda, Miguel Ángel (MDPI, 2021-11-17)Cement hydration is a very complex set of processes. The evolution of the crystalline phases during hydration can be accurately followed by X-ray powder diffraction data evaluated by the Rietveld method. However, accurate ... -
Ammonia effects on proton conductivity properties of coordination polymers
Pérez Colodrero, Rosario M.; Salcedo, Inés R.; Bazaga-García, Montse; Olivera-Pastor, Pascual; Moreno-Real, Laureano; [et al.] (2016-09-22)Crystalline metal phosphonates are referred to as a type of structurally versatile coordination polymers [1]. Many of them contain guest molecules (H2O, heterocyclics, etc.), acidic sites and, furthermore, their structure ... -
Cementos de arcillas calcinadas y caliza preparados en la Universidad de Málaga
Gomez-de-la-Torre, Maria de los Angeles; Santacruz-Cruz, Maria Isabel; Cuesta-García, Ana María; Bernal, Isabel M.R.; Redondo-Soto, Cinthya; [et al.] (2022)Adjuto documento -
Electrochemical and photochemical applications of multifunctional metal phosphonates
Salcedo, Inés R. (UMA Editorial, 2021-02-09)In this PhD thesis, proton conductivity, photocatalytic and luminescence properties of synthesised multifunctional metal phosphonates have been studied. Iron and zinc derivatives of the R,S hydroxyphosphonoacetic acid ... -
From light to heavy alkali metal tetraphosphonates (M = Li, Na, K, Rb, Cs): cation size-induced structural diversity and waterfacilitated proton conductivity
Salcedo, Inés R.; Pérez Colodrero, Rosario M.; Bazaga-García, Montse; Vasileiou, Antonia; Papadaki, Maria; [et al.] (The Royal Society of Chemistry, 2018-09)A family of alkali metal-based frameworks containing the tetraphosphonate ligand hexamethylenediamine- N,N,N′,N′-tetrakisIJmethylenephosphonic acid), HDTMP, is reported. A cation size-induced structural diversity, from ... -
High-Throughput Synthesis of Pillared-Layered Magnesium Tetraphosphonate Coordination Polymers: Framework Interconversions and Proton Conductivity Studies
Pérez Colodrero, Rosario M.; Salcedo, Inés R.; Bazaga-García, Montse; Barouda, Eleni; Papadaki, Maria; [et al.] (MDPI, www.mdpi.com/journal/inorganics, 2018-09-11)Novel pillared-layered framework materials were synthesized by high-throughput or microwave-assisted methodology that contain Mg2+ and the zwitterionic linker HDTMP (hexamethylenediamine-N,N,N0,N0-tetrakis(methylenephosphonic ... -
In situ high pressure powder diffraction study of proton conductors based on metal phosphonates
Bazaga-García, Montse; Pérez Colodrero, Rosario M.; Olivera-Pastor, Pascual; Losilla, Enrique R.; Salcedo, Inés R.; [et al.] (2015-06-30)Soft Porous Metal Organic frameworks (MOFs) are referred to as a class of coordination polymers that exhibit structural flexibility in response to guest interactions or physical stimuli [1]. By combining softness and ... -
Layered Lanthanide Sulfophosphonates and Their Proton Conduction Properties in Membrane Electrode Assemblies
Bazaga-García, Montse; Salcedo, Inés R.; Pérez Colodrero, Rosario M.; Xanthopoulos, Konstantinos; Villemin, Didier; [et al.] (ACS publications, 2019-11-07)Metal phosphonates containing acidic groups exhibit a wide range of proton conduction properties, which may enhance the performance of membrane electrode assemblies (MEAs). In this work, focus is placed on proton conduction ... -
Luminescent and Proton Conducting Lanthanide Coordination Networks Based On a Zwitterionic Tripodal Triphosphonate
Bazaga-García, Montse; Angeli, Giasemi K.; Papathanasiou, Konstantinos E.; Salcedo, Inés R.; Olivera-Pastor, Pascual; [et al.] (American Chemical Society, 2016-07-14)The synthesis, structural characterization, luminescence properties, and proton conduction performance of a new family of isostructural cationic 2D layered compounds are reported. These have the general formula ... -
New directions in metal phosphonate and fhosphinate chemistry
Shearan, Stephen J.I.; Stock, Norbert; Emmerling, Franziska; Demel, Jan; Wright, Paul A.; [et al.] (MDPI www.mdpi.com/journal/crystals, 2019-05-24)In September 2018, the First EuropeanWorkshop on Metal Phosphonates Chemistry brought together some prominent researchers in the field of metal phosphonates and phosphinates with the aim of discussing past and current ... -
New multifuncional divalent metal-coordinated sulfophosphonates: structures and proton conductivities
Bazaga-García, Montse; Pérez Colodrero, Rosario M.; Salcedo, Inés R.; Olivera-Pastor, Pascual; Cabeza-Diaz, Aurelio; [et al.] (2021-01-29)Metal phosphonate-based coordination polymers are structurally versatile multifunctional compounds that may contain a number of acidic groups such as P-OH; SO3H, COOH, N+-H…These features result in formation of extended ... -
New Multifunctional Lanthanide and Zr(IV) Phosphonates Derived from the 5-(dihydroxyphosphoryl) Isophthalate Ligand as Proton Conductors
Salcedo, Inés R.; Pérez Colodrero, Rosario M.; Olivera-Pastor, Pascual; Losilla, Enrique R.; Zon, Jerzy; [et al.] (2019-06-06)Metal phosphonates are essentially acidic solids featured by groups such as P-OH, -COOH, etc. Moreover, the presence of coordination and lattice water molecules favors the formation of H-bond networks, which make these ... -
New multifunctional sulfonato-containing metal phosphonates proton conductors
Salcedo, Inés R.; Bazaga-García, Montse; Pérez Colodrero, Rosario M.; Xanthopoulos, Konstantinos; Demadis, Konstantinos D.; [et al.] (2018-10-01)Anchoring of acidic functional groups to organic linkers acting as ligands in metal phosphonates has been demonstrate to be a valid strategy to develop new proton conductor materials, which exhibit tunable properties and ... -
NH3/H2O-mediated proton conductivity and photocatalytic behaviour of Fe(II)-hydroxyphosphonoacetate and M(II)-substituted derivatives
Salcedo, Inés R.; Bazaga-García, Montse; Cuesta-Garcia, Ana Maria; Ramirez-Losilla, Enrique; Demadis, Konstantinos D.; [et al.] (The Royal Society of Chemistry, 2019-12-27)Synthesis redesign and derivatisation of Fe(II)-hydroxyphosphonoacetate, incorporating different ammonia loads and M(II) isomorphic substitutions (M = Mn, Co and Zn), have been implemented. The NH3 adsorption led to materials ... -
Phase Transformation Dynamics in Sulfate-Loaded Lanthanide Triphosphonates. Proton Conductivity and Application as Fillers in PEMFCs
Salcedo, Inés R.; Pérez Colodrero, Rosario M.; Bazaga-García, Montse; López González, María del Mar; del Río, Carmen; [et al.] (ACS Publications. American Chemical Society, 2021)Phase transformation dynamics and proton conduction properties are reported for cationic layer-featured coordination polymers derived from the combination of lanthanide ions (Ln3+) with nitrilo-tris(methylenephosphonic ... -
Phosphonate Decomposition-Induced Polyoxomolybdate Dumbbell-Type Cluster Formation: Structural Analysis, Proton Conduction, and Catalytic Sulfoxide Reduction
Armakola, Eirini; Salcedo, Inés R.; Bazaga-García, Montse; Mezei, Gellert; Cabeza-Diaz, Aurelio; [et al.] (ACS publications, 2019-08-12)The reaction of MoO4^2− with a number of phosphonic acids [bis-(phosphonomethyl)glycine, R,S-hydroxyphosphonoacetic acid, 1-hydroxyethane-1,1-diphosphonic acid, phenylphosphonic acid, aminotris(methylene phosphonic acid), ... -
Proton conductivity and luminiscence properties of lanthanide aminotriphosphonates
Bazaga-García, Montse; Angeli, Giasemi K.; Papathanasiou, Konstantinos E.; Salcedo, Inés R.; Olivera-Pastor, Pascual; [et al.] (2016)Metal phosphonates are multifunctional solids with tunable properties, such as internal H-bond networks, and high chemical and thermal stability [1]. In the present work, we describe the synthesis, structural characterization, ... -
Proton Conductivity in Sulfate-Containing Lanthanide Nitrilotris-methylphosphonates
Salcedo, Inés R.; Cabeza-Diaz, Aurelio; Bazaga-García, Montse; Pérez Colodrero, Rosario M.; Choquesillo-Lazarte, Duane; [et al.] (2019-09-12)Multifunctional metal phosphonates are coordination polymers (CPs) whose structures are usually composed of extended hydrogen-bond networks and thus making them potential candidates as proton conductors [1]. Moreover, these ... -
Proton conductivity of lanthanide nitrilotris-methylphosphonates
Salcedo, Inés R.; Bazaga-García, Montse; Pérez Colodrero, Rosario M.; Olivera-Pastor, Pascual; Losilla, Enrique R.; [et al.] (2017-07-10)Multifunctional metal phosphonates are acidic coordination polymers (CPs) with remarkable stability and proton conducting properties owing to their structure is usually composed of extended hydrogen-bond networks that favor ... -
PXRD and PDF analysis of multifunctional lanthanide nitrilotris-methylphosphonate-based proton conductors
Pérez Colodrero, Rosario M.; Cabeza-Diaz, Aurelio; Salcedo, Inés R.; Bazaga-García, Montse; Olivera-Pastor, Pascual (2017-10-17)Metal phosphonates are multifunctional solids which possess tunable properties, such as H-bond networks, while exhibiting high chemical and thermal stability. Depending on the protonation of the ligand, different crystalline ...