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Listar por autor "Salcedo, Inés R."
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New Multifunctional Lanthanide and Zr(IV) Phosphonates Derived from the 5-(dihydroxyphosphoryl) Isophthalate Ligand as Proton Conductors
Salcedo, Inés R.; Pérez-Colodrero, Rosario Mercedes; Olivera-Pastor, Pascual; Losilla, Enrique R.; Zon, Jerzy; Zareba, Jan K.; Costantino, Ferdinando; Cabeza-Díaz, Aurelio; Bazaga-García, Montse[et al.] (2019-06-06)Metal phosphonates are essentially acidic solids featured by groups such as P-OH, -COOH, etc. Moreover, the presence of coordination and lattice water molecules favors the formation of H-bond networks, which make these ... -
New multifunctional sulfonato-containing metal phosphonates proton conductors
Salcedo, Inés R.; Bazaga-García, Montse; Pérez-Colodrero, Rosario Mercedes; Xanthopoulos, Konstantinos; Demadis, Konstantinos D.; Stock, Norbert; Cabeza-Díaz, Aurelio; Ramírez-Losilla, Enrique; Olivera-Pastor, Pascual[et al.] (2018-10-01)Anchoring of acidic functional groups to organic linkers acting as ligands in metal phosphonates has been demonstrate to be a valid strategy to develop new proton conductor materials, which exhibit tunable properties and ... -
NH3/H2O-mediated proton conductivity and photocatalytic behaviour of Fe(II)-hydroxyphosphonoacetate and M(II)-substituted derivatives
Salcedo, Inés R.; Bazaga-García, Montse; Cuesta-García, Ana María; Ramírez-Losilla, Enrique; Demadis, Konstantinos D.; Olivera-Pastor, Pascual; Pérez-Colodrero, Rosario Mercedes; Cabeza-Díaz, Aurelio[et al.] (The Royal Society of Chemistry, 2019-12-27)Synthesis redesign and derivatisation of Fe(II)-hydroxyphosphonoacetate, incorporating different ammonia loads and M(II) isomorphic substitutions (M = Mn, Co and Zn), have been implemented. The NH3 adsorption led to materials ... -
La odisea de medir PDF con un difractómetro “convencional”
En esta ponencia se presenta la puesta a punto del difractómetro D8 Advance (Bruker S.L.) para la adquisición de datos de laboratorio de PDF (Pair Distribution Function) junto con los resultados obtenidos. -
Phase Transformation Dynamics in Sulfate-Loaded Lanthanide Triphosphonates. Proton Conductivity and Application as Fillers in PEMFCs
Salcedo, Inés R.; Pérez-Colodrero, Rosario Mercedes; Bazaga-García, Montse; López González, María del Mar; Del Río, Carmen; Xanthopoulos, Konstantinos; Demadis, Konstantinos D.; Hix, Gary B.; Furasova, Aleksandra D.; Choquesillo-Lazarte, Duane; Olivera-Pastor, Pascual; Cabeza-Díaz, Aurelio[et al.] (ACS Publications. American Chemical Society, 2021)Phase transformation dynamics and proton conduction properties are reported for cationic layer-featured coordination polymers derived from the combination of lanthanide ions (Ln3+) with nitrilo-tris(methylenephosphonic ... -
Phosphonate Decomposition-Induced Polyoxomolybdate Dumbbell-Type Cluster Formation: Structural Analysis, Proton Conduction, and Catalytic Sulfoxide Reduction
Armakola, Eirini; Salcedo, Inés R.; Bazaga-García, Montse; Mezei, Gellert; Cabeza-Díaz, Aurelio; Fernandes, Tiago A.; Kirillov, Alexander M.; Demadis, Konstantinos D.[et al.] (ACS publications, 2019-08-12)The reaction of MoO4^2− with a number of phosphonic acids [bis-(phosphonomethyl)glycine, R,S-hydroxyphosphonoacetic acid, 1-hydroxyethane-1,1-diphosphonic acid, phenylphosphonic acid, aminotris(methylene phosphonic acid), ... -
Proton Conduction Properties of Metal phosphonates and Application as Fillers in PEMFCs
Bazaga-García, Montse; Cabeza-Díaz, Aurelio; Pérez-Colodrero, Rosario Mercedes; Salcedo, Inés R.; Vílchez-Cózar, Álvaro; Olivera-Pastor, Pascual[et al.] (2022-07)Metal phosphonate (MP)-based coordination polymers (CPs) are structurally versatile multifunctional compounds containing different acidic groups such as P-OH; SO3H, COOH, N+-H, etc. These features result in the formation ... -
Proton conductivity and luminiscence properties of lanthanide aminotriphosphonates
Bazaga-García, Montse; Angeli, Giasemi K.; Papathanasiou, Konstantinos E.; Salcedo, Inés R.; Olivera-Pastor, Pascual; Losilla, Enrique R.; Choquesillo-Lazarte, Duane; Hix, Gary B.; Cabeza-Díaz, Aurelio; Demadis, Konstantinos D.[et al.] (2016)Metal phosphonates are multifunctional solids with tunable properties, such as internal H-bond networks, and high chemical and thermal stability [1]. In the present work, we describe the synthesis, structural characterization, ... -
Proton Conductivity in Sulfate-Containing Lanthanide Nitrilotris-methylphosphonates
Salcedo, Inés R.; Cabeza-Díaz, Aurelio; Bazaga-García, Montse; Pérez-Colodrero, Rosario Mercedes; Choquesillo-Lazarte, Duane; Hix, Gary B.; Ramírez-Losilla, Enrique; Olivera-Pastor, Pascual[et al.] (2019-09-12)Multifunctional metal phosphonates are coordination polymers (CPs) whose structures are usually composed of extended hydrogen-bond networks and thus making them potential candidates as proton conductors [1]. Moreover, these ... -
Proton conductivity of lanthanide nitrilotris-methylphosphonates
Salcedo, Inés R.; Bazaga-García, Montse; Pérez-Colodrero, Rosario Mercedes; Olivera-Pastor, Pascual; Losilla, Enrique R.; Cabeza-Díaz, Aurelio[et al.] (2017-07-10)Multifunctional metal phosphonates are acidic coordination polymers (CPs) with remarkable stability and proton conducting properties owing to their structure is usually composed of extended hydrogen-bond networks that favor ... -
PXRD and PDF analysis of multifunctional lanthanide nitrilotris-methylphosphonate-based proton conductors
Pérez-Colodrero, Rosario Mercedes; Cabeza-Díaz, Aurelio; Salcedo, Inés R.; Bazaga-García, Montse; Olivera-Pastor, Pascual (2017-10-17)Metal phosphonates are multifunctional solids which possess tunable properties, such as H-bond networks, while exhibiting high chemical and thermal stability. Depending on the protonation of the ligand, different crystalline ... -
Structural Landscape and Proton Conduction of Lanthanide 5-(Dihydroxyphosphoryl)isophthalates
Salcedo, Inés R.; Bazaga-García, Montse; Pérez-Colodrero, Rosario Mercedes; Vílchez-Cózar, Álvaro; Cañamero-Cebrián, Fernando; Olivera-Pastor, Pascual; Zareba, Jan K.; Cabeza-Díaz, Aurelio[et al.] (ACS Publications, 2024)Metal phosphonate-carboxylate compounds repre-sent a promising class of materials for proton conductionapplications. This study investigates the structural, thermal, andproton conduction properties of three groups of ... -
Structural study of the local order in ammonia-modulated FE(II) hydroxyphosphonoacetate proton conductors
Bazaga-García, Montse; Cabeza-Díaz, Aurelio; Pérez-Colodrero, Rosario Mercedes; Salcedo, Inés R.; Olivera-Pastor, Pascual; Losilla, Enrique R.[et al.] (2017-10-17)Layered Fe(II) carboxiphosphonate, Fe-HPAA·2H2O, is a crystalline multifunctional coordination polymer exhibiting properties as photocatalyst and proton conductor. Postsynthesis modification by ammonia/water adsorption ... -
Structural variability in M2+ 2-hydroxyphosphonoacetate moderate proton conductors
Pérez-Colodrero, Rosario Mercedes; Salcedo, Inés R.; Bazaga-García, Montse; Milla-Pérez, Diego F.; Durán-Martín, Jonatan D.; Ramírez-Losilla, Enrique; Moreno-Real, Laureano; Rius, Jordi; García-Aranda, Miguel Ángel; Demadis, Konstantinos D.; Olivera-Pastor, Pascual; Cabeza-Díaz, Aurelio[et al.] (De Gruyter, 2017)The structural variability of two series of Mg2+- and Zn2+- 2-hydroxyphosphonoacetates have been studied in the range of 25–80 °C and 95 % relative humidity in order to correlate the structure with the proton conductivity ... -
Structure-properties correlations in divalent metal phosphonates
Pérez-Colodrero, Rosario Mercedes; Bazaga-García, Montse; Olivera-Pastor, Pascual; Ramírez-Losilla, Enrique; Salcedo, Inés R.; García-Aranda, Miguel Ángel; Cabeza-Díaz, Aurelio[et al.] (2016)Crystalline metal phosphonates may offer acidic sites, structural flexibility and guest molecules (H2O, heterocyclics, etc.) which can act as proton carriers. In addition, some frameworks are also amenable for post‐synthesis ... -
Synthesis and characterization of M(II) phosphonates (M = Fe, Co, Zn, Mn) as precursors for PEMFCs electrocatalysts
López Vergara, Adrián; Salcedo, Inés R.; Bazaga-García, Montse; Olivera-Pastor, Pascual; Cabeza-Díaz, Aurelio; Losilla, Enrique R.; Porras-Vázquez, José Manuel[et al.] (2018-11-15)Metal phosphonates are promising precursors for applications such as proton conductivity [1] and catalysis [2]. Specifically, upon calcination metal polyphosphates are generated that can be used as non-noble metal alternatives ... -
Synthesis and properties of novel lanthanide carboxyphosphonates
Pérez-Colodrero, Rosario Mercedes; Salcedo, Inés R.; Bazaga-García, Montse; Zon, Jerzy; Zareba, Jan K.; Olivera-Pastor, Pascual; Cabeza-Díaz, Aurelio[et al.] (2021-02-01)Metal phosphonates are essentially acidic solids featured by groups such as P-OH, -COOH, etc. The presence of bound and lattice water favors the formation of H-bond networks, which make these compounds appropriate as proton ... -
Synthesis and proton conduction properties of lanthanide amino-sulfophosphonates
Cabeza-Díaz, Aurelio; Bazaga-García, Montse; Pérez-Colodrero, Rosario Mercedes; Salcedo, Inés R.; Villemin, Didier; Olivera-Pastor, Pascual; Losilla, Enrique R.[et al.] (2016)Crystalline acid-functionalized metal phosphonates are potential candidates as proton conducting electrolytes. Their frameworks can be chemically modified to contain proton carriers such as acidic groups (P-OH; -SO3H, ... -
Synthesis and proton conduction properties of lanthanide amino-sulfophosphonates
Salcedo, Inés R.; Quintero, Estefanía; Bazaga-García, Montse; Pérez-Colodrero, Rosario Mercedes; Olivera-Pastor, Pascual; Ramírez-Losilla, Enrique; Cabeza-Díaz, Aurelio[et al.] (2018-06-28)Acidic groups-containing metal phosphonates exhibit a wide range of proton conductivity depending on the water content and functionality. Moreover, this property can be enhanced by appropriate post-synthesis chemical ... -
Three-Component Copper-Phosphonate-Auxiliary Ligand Systems: Proton Conductors and Efficient Catalysts in Mild Oxidative Functionalization of Cycloalkanes
Armakola, Eirini; Pérez-Colodrero, Rosario Mercedes; Bazaga-García, Montse; Salcedo, Inés R.; Choquesillo-Lazarte, Duane; Cabeza-Díaz, Aurelio; Kirillova, Marina V.; Kirillov, Alexander M.; Demadis, Konstantinos D.[et al.] (ACS publications, 2018-08-13)The synthesis, structural characterization, topological analysis, proton conductivity, and catalytic properties are reported of two Cu(II)-based compounds, namely a dinuclear Cu(II) complex [Cu2(μ-VPA)2(phen)2(H2O)2]· 8H2O ...