Listar por autor "Cabeza-Díaz, Aurelio"
Mostrando ítems 41-60 de 86
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Phase Transformation Dynamics in Sulfate-Loaded Lanthanide Triphosphonates. Proton Conductivity and Application as Fillers in PEMFCs
Salcedo, Inés R.; Pérez-Colodrero, Rosario Mercedes
; Bazaga-García, Montse; López González, María del Mar; Del Río, Carmen; Xanthopoulos, Konstantinos; Demadis, Konstantinos D.; Hix, Gary B.; Furasova, Aleksandra D.; Choquesillo-Lazarte, Duane; Olivera-Pastor, Pascual; Cabeza-Díaz, Aurelio[et al.] (ACS Publications. American Chemical Society, 2021)
Phase transformation dynamics and proton conduction properties are reported for cationic layer-featured coordination polymers derived from the combination of lanthanide ions (Ln3+) with nitrilo-tris(methylenephosphonic ... -
Phosphonate Decomposition-Induced Polyoxomolybdate Dumbbell-Type Cluster Formation: Structural Analysis, Proton Conduction, and Catalytic Sulfoxide Reduction
Armakola, Eirini; Salcedo, Inés R.; Bazaga-García, Montse; Mezei, Gellert; Cabeza-Díaz, Aurelio; Fernandes, Tiago A.; Kirillov, Alexander M.; Demadis, Konstantinos D.[et al.] (ACS publications, 2019-08-12)
The reaction of MoO4^2− with a number of phosphonic acids [bis-(phosphonomethyl)glycine, R,S-hydroxyphosphonoacetic acid, 1-hydroxyethane-1,1-diphosphonic acid, phenylphosphonic acid, aminotris(methylene phosphonic acid), ... -
Photodegradation of Phenol over a Hybrid Organo-Inorganic Material: Iron(II) Hydroxyphosphonoacetate
Bazaga-García, Montse; Cabeza-Díaz, Aurelio; Olivera-Pastor, Pascual; Santacruz-Cruz, María Isabel; Pérez-Colodrero, Rosario Mercedes; García-Aranda, Miguel Ángel[et al.] (American Chemical Society, 2012-06-20)
Water treatment is a hot topic, and it will become much more important in the decades ahead. Advanced oxidation processes are being increasingly used for organic contaminant removal, for example using photo-Fenton reactions. ... -
Preparation and characterization of phosphorus-containing electrocatalyst for OER, HER and ORR.
Vílchez-Cózar, Álvaro; Bazaga-García, Montse; Olivera-Pastor, Pascual; Cabeza-Díaz, Aurelio; Pérez-Colodrero, Rosario Mercedes (2022-11)
Phosphorus-based materials, such as transition metal phosphides and phosphates/pyrophosphates, have drawn considerable attention as promising alternatives to noble metal-based catalysts (Pt, Ru, Ir) owing to their widely ... -
Preparation of N-doped Carbon/Metal Phosphides as Promising Trifunctional Electrocatalysts Toward the OER, ORR and HER
Vílchez-Cózar, Álvaro; Bazaga-García, Montse; Marrero-López, David; Olivera-Pastor, Pascual; Demadis, Konstantinos D.; Cabeza-Díaz, Aurelio; Pérez-Colodrero, Rosario Mercedes[et al.] (2022-07-27)
Sustainable energy storage and conversion technologies, such as electrochemical water splitting and fuel cells, attracts increasing attention as alternative processes to advance toward a global decarbonation. However, the ... -
Processing and characterisation of Calcium SulfoAluminate (CSA) eco-cements coated with a hybrid organo-inorganic material for photocatalytic applications
Morales-Cantero, Alejandro; Cabeza-Díaz, Aurelio; Gómez-de-la-Torre, María de los Ángeles; García-Aranda, Miguel Ángel; Santacruz-Cruz, María Isabel (2015-07-27)
On the one hand, Calcium SulfoAluminate (CSA) eco-cements are receiving increasing attention since their manufacture produces up to 40% less CO2 than ordinary Portland cement (OPC). In addition, they show interesting ... -
Properties and Applications of Metal Phosphates and Pyrophosphates as Proton Conductors
Pérez-Colodrero, Rosario Mercedes; Olivera-Pastor, Pascual; Cabeza-Díaz, Aurelio; Bazaga-García, Montse (MDPI, 2022-02-09)
We review the progress in metal phosphate structural chemistry focused on proton conductivity properties and applications. Attention is paid to structure–property relationships, which ultimately determine the potential ... -
Proton Conduction Properties of Metal phosphonates and Application as Fillers in PEMFCs
Bazaga-García, Montse; Cabeza-Díaz, Aurelio; Pérez-Colodrero, Rosario Mercedes; Salcedo, Inés R.; Vílchez-Cózar, Álvaro; Olivera-Pastor, Pascual[et al.] (2022-07)
Metal phosphonate (MP)-based coordination polymers (CPs) are structurally versatile multifunctional compounds containing different acidic groups such as P-OH; SO3H, COOH, N+-H, etc. These features result in the formation ... -
Proton conductivity and luminiscence properties of lanthanide aminotriphosphonates
Bazaga-García, Montse; Angeli, Giasemi K.; Papathanasiou, Konstantinos E.; Salcedo, Inés R.; Olivera-Pastor, Pascual; Losilla, Enrique R.; Choquesillo-Lazarte, Duane; Hix, Gary B.; Cabeza-Díaz, Aurelio; Demadis, Konstantinos D.[et al.] (2016)
Metal phosphonates are multifunctional solids with tunable properties, such as internal H-bond networks, and high chemical and thermal stability [1]. In the present work, we describe the synthesis, structural characterization, ... -
Proton Conductivity in Sulfate-Containing Lanthanide Nitrilotris-methylphosphonates
Salcedo, Inés R.; Cabeza-Díaz, Aurelio; Bazaga-García, Montse; Pérez-Colodrero, Rosario Mercedes; Choquesillo-Lazarte, Duane; Hix, Gary B.; Ramírez-Losilla, Enrique; Olivera-Pastor, Pascual[et al.] (2019-09-12)
Multifunctional metal phosphonates are coordination polymers (CPs) whose structures are usually composed of extended hydrogen-bond networks and thus making them potential candidates as proton conductors [1]. Moreover, these ... -
Proton conductivity of lanthanide nitrilotris-methylphosphonates
Salcedo, Inés R.; Bazaga-García, Montse; Pérez-Colodrero, Rosario Mercedes; Olivera-Pastor, Pascual; Losilla, Enrique R.; Cabeza-Díaz, Aurelio[et al.] (2017-07-10)
Multifunctional metal phosphonates are acidic coordination polymers (CPs) with remarkable stability and proton conducting properties owing to their structure is usually composed of extended hydrogen-bond networks that favor ... -
Proton conductivity of multifunctional metal phosphonate frameworks
Cabeza-Díaz, Aurelio; Bazaga-García, Montse; Pérez-Colodrero, Rosario Mercedes; Papadaki, M.; Olivera-Pastor, Pascual; Losilla, Enrique R.; León-Reina, Laura; Moreno-Real, Laureano; García-Aranda, Miguel Ángel; Demadis, Konstantinos D.[et al.] (2015-03-23)
Metal phosphonates exhibit attractive characteristics for proton conductivity, such as tunable functionality, chemical and thermal stability and the existence of H-bond networks with acidic protons within their structure.1 In ... -
Proton conductivity properties of novel tin(II) phosphonates
Cañamero-Cebrián, Fernando; Cabeza-Díaz, Aurelio; Vílchez-Cózar, Álvaro; Bazaga-García, Montse; Ramírez-Losilla, Enrique; Olivera-Pastor, Pascual; Pérez-Colodrero, Rosario Mercedes[et al.] (2024-01-16)
Metal phosphonates (MPs), a subclass of coordination polymers, may exhibit acidic groups such as P-OH, SO3H, COOH, N+-H, etc. Combining these features with interesting metals make them highly appealing in the field of fuel ... -
Proton Conductors based on Metal Phosphonate Hybrid Materials for PEM Fuel Cells
Cabeza-Díaz, Aurelio; Pérez-Colodrero, Rosario Mercedes; Bazaga-García, Montse; Hernández Alonso, Daniel; Compaña Prieto, José Manuel; Olivera-Pastor, Pascual; Losilla, Enrique R.; García-Aranda, Miguel Ángel; León-Reina, Laura[et al.] (2014-06-25)
The necessity of energy and power generation is constantly growing. Fossils fuels are quickly becoming unsatisfactory substrates due to both their emission of pollutants and their finite expectancy. Fuel cells are one of ... -
PXRD and PDF analysis of multifunctional lanthanide nitrilotris-methylphosphonate-based proton conductors
Pérez-Colodrero, Rosario Mercedes; Cabeza-Díaz, Aurelio; Salcedo, Inés R.; Bazaga-García, Montse; Olivera-Pastor, Pascual (2017-10-17)
Metal phosphonates are multifunctional solids which possess tunable properties, such as H-bond networks, while exhibiting high chemical and thermal stability. Depending on the protonation of the ligand, different crystalline ... -
Relationship between the Structure and Transport Properties in the Ce1−xLaxO2−x/2 System
Zamudio-García, Javier; Porras-Vázquez, José Manuel; Canales-Vázquez, J.; Cabeza-Díaz, Aurelio; Losilla, Enrique R.; Marrero-López, David[et al.] (American Chemical Society, 2019-06-25)
La-doped CeO2 materials have been widely investigated for potential applications in different high-temperature electrochemical devices, such as fuel cells and ceramic membranes for hydrogen production. However, the crystal ... -
Single and solid solutions metal carboxyphosphonates as precursors for phosphorous-containing electrocatalysts
López Vergara, Adrián; El-Refaei, S.M.; Russo, Patricia A.; Vilchez, A; Losilla, Enrique R.; Porras-Vázquez, José Manuel; Olivera-Pastor, Pascual; Pinna, N; Cabeza-Díaz, Aurelio[et al.] (2019-07-19)
Co1-xFex-HPAA metal phosphonates were prepared and pyrolyzed under N2 and H2/Ar flows. The result-ing powders were structural and electrochemically characterised by XRD and CV, respectively. The ob-tained materials possess ... -
Structural and Proton Conductivity Studies of Fibrous π-Ti2O(PO4)2·2H2O: Application in Chitosan- Based Composite Membranes
Babaryk, Artem A.; Adawy, Alaa; García, Inés; Trobajo, Camino; Amghouz, Zakariae; Pérez-Colodrero, Rosario Mercedes; Cabeza-Díaz, Aurelio; Olivera-Pastor, Pascual; Bazaga-García, Montse; Dos-Santos-Gómez, Lucía[et al.] (The Royal Society of Chemistry, 2021)
Although the fibrous polymorphic modification of titanium phosphate, π-Ti2O(PO4)2·2H2O (π-TiP) is known for decades, its crystal structure has remained unsolved. Herewith we report the crystal structure of π-TiP at a room ... -
Structural Characterization of Transition-Metal Carboxyethanephosphonates as Precursors of Electrocatalysts
Sánchez Caballero, Abraham; Vílchez-Cózar, Álvaro; Cabeza-Díaz, Aurelio; Bazaga-García, Montse; Olivera-Pastor, Pascual; Pérez-Colodrero, Rosario Mercedes[et al.] (2023)
Phosphorus-containing coordination polymers (CPs) are considered as one of the most promising precursors of materials alternative to the highly expensive commercial catalysts (Pt, Ru and Ir) used in polymeric fuel cells ... -
Structural Landscape and Proton Conduction of Lanthanide 5-(Dihydroxyphosphoryl)isophthalates
Salcedo, Inés R.; Bazaga-García, Montse; Pérez-Colodrero, Rosario Mercedes; Vílchez-Cózar, Álvaro; Cañamero-Cebrián, Fernando; Olivera-Pastor, Pascual; Zareba, Jan K.; Cabeza-Díaz, Aurelio[et al.] (ACS Publications, 2024)
Metal phosphonate-carboxylate compounds repre-sent a promising class of materials for proton conductionapplications. This study investigates the structural, thermal, andproton conduction properties of three groups of ...