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“Breathing” in Adsorbate-Responsive Metal Tetraphosphonate Hybrid Materials
(Wiley-VCH Verlag GmbH&Co. KGaA, Weinheim, 2009-05-28)
The structures of various layered calcium tetraphosphonates (CaH6DTMP; H8DTMP=hexamethyl- tetrakis(methylenephosphonic acid)), have been determined. Starting from CaH6DTMP·2H2O, thermal treatment and subsequent exposure ...
Tuning Proton Conductivity in A Multifunctional Calcium Phosphonate Hybrid Framework
(2014-06-25)
Multi-chelating phosphonate ligands are organic linkers alternative to polycarboxylates and other ligands providing synthetic access to a number of thermally- and chemically-stable MOFs [1]. Metal phosphonates are amenable ...
Proton Conductors based on Metal Phosphonate Hybrid Materials for PEM Fuel Cells
(2014-06-25)
The necessity of energy and power generation is constantly growing. Fossils fuels are quickly becoming unsatisfactory substrates due to both their emission of pollutants and their finite expectancy. Fuel cells are one of ...
Structural Variability in Multifunctional Metal Xylenediaminetetraphosphonate Hybrids
(2013)
The two cornerstones in the field of MOFs are the Secondary Building Units (SBU’s or “bricks”) and the organic linkers. The structural tunability of crystalline MOFs coupled, when possible, with high chemical and thermal ...
Proton conductivity of multifunctional metal phosphonate frameworks
(2015-03-23)
Metal phosphonates exhibit attractive characteristics for proton conductivity, such as tunable functionality, chemical and thermal stability and the existence of H-bond networks with acidic protons within their structure.1
In ...