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Tuning Proton Conductivity in Alkali Metal Phosphonocarboxylates by Cation Size-Induced and Water-Facilitated Proton Transfer Pathways
(American Chemical Society, 2014-12-20)
The structural and functional chemistry of a family of alkali-metal ions with racemic R,S-hydroxyphosphonoacetate (M-HPAA; M = Li, Na, K, Cs) are reported. Crystal structures were determined by X-ray data (Li+, powder ...
Guest Molecule-Responsive Functional Calcium Phosphonate Frameworks for Tuned Proton Conductivity
(American Chemical Society, 2014-03-18)
We report the synthesis, structural characterization, and functionality of an open-framework hybrid that combines Ca2+ ions and the rigid polyfunctional ligand 5-(dihydroxyphosphoryl) isophthalic acid (PiPhtA). Ca-PiPhtA-I ...
Tuning Proton Conductivity in A Multifunctional Calcium Phosphonate Hybrid Framework
(2014-06-25)
Multi-chelating phosphonate ligands are organic linkers alternative to polycarboxylates and other ligands providing synthetic access to a number of thermally- and chemically-stable MOFs [1]. Metal phosphonates are amenable ...
Proton Conductors based on Metal Phosphonate Hybrid Materials for PEM Fuel Cells
(2014-06-25)
The necessity of energy and power generation is constantly growing. Fossils fuels are quickly becoming unsatisfactory substrates due to both their emission of pollutants and their finite expectancy. Fuel cells are one of ...