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Powder diffraction at ALBA synchrotron
(2017-03-17)
This talk is devoted to explain the uses of powder diffraction at MSPD (material science and powder diffraction) of ALBA synchrotron light source. General characteristics of the beamline are: Station 1 - High Pressure ...
Synthesis of active Belite-Alite-Ye'elimite clinker (BAY)
(2016-06-29)
Ordinary Portland cement (OPC) is an environmentally contentious material, as for every ton of OPC produced, on average, 0.97 tons of CO2 are released. Ye'elimite-rich cements are considered as eco-cements because their ...
Belite cements and their activation
(Elsevier, 2020-11)
Belite cements, BCs, containing mainly belite, alite and calcium aluminates, are currently used as low heat cements.
These binders produce high amounts of C–S–H gel and have very good durability properties which are
reviewed. ...
Belite hydration at high temperature and pressure by in situ synchrotron powder diffraction
(2020-10-16)
Portland cements are currently used as Oil‐Well‐Cements for the sheath between the metal casing
and the borehole. At high pressures and temperatures, the resulting C-S-H gel(s) is partly unstable
and it can react to give ...
Calcium aluminate cement conversion analysed by ptychographic nanotomography
(Elsevier, 2020-08-17)
Calcium aluminate cements are used for special applications but are nowadays banned for general
structural purposes due to the calcium aluminate hydrate conversion, that has led, for concretes
fabricated with high water ...
Guest Molecule-Responsive Functional Calcium Phosphonate Frameworks for Tuned Proton Conductivity
(American Chemical Society, 2014-03-18)
We report the synthesis, structural characterization, and functionality of an open-framework hybrid that combines Ca2+ ions and the rigid polyfunctional ligand 5-(dihydroxyphosphoryl) isophthalic acid (PiPhtA). Ca-PiPhtA-I ...
High pressure and temperature spinning capillary cell for in-situ synchrotron X-ray powder diffraction
(2019)
In situ research of materials under moderate pressures (hundreds of bar) is essential in many scientific fields. These range from gas sorption to chemical and biological processes. One industrially important discipline is ...
High Proton Conductivity in a Flexible, Cross-Linked, Ultramicroporous Magnesium Tetraphosphonate Hybrid Framework
(American Chemical Society, 2012-07-03)
Multifunctional materials, especially those combining two or more properties of interest, are attracting immense attention due to their potential applications. MOFs, metal organic frameworks, can be regarded as multifunctional ...
Local structure and Ca/Si ratio in C-S-H gels from hydration of blends of tricalcium silicate and silica fume
(Elsevier, 2021-03)
At the microscale, C-S-H gels from alite, or neat Portland cements, has a Ca/Si ratio close to 1.80. At the nanoscale, C-S-H is described by a defective tobermorite structure which allows a maximum Ca/Si ratio close to ...
Multifunctional lanthanum tetraphosphonates: Flexible, ultramicroporous and proton-conducting hybrid frameworks
(The Royal Society of Chemistry, 2012)
A new flexible ultramicroporous solid, La(H5DTMP)·7H2O (1), has been crystallized at room temperature using the tetraphosphonic acid H8DTMP, hexamethylenediamine-N,N,N′,N′-tetrakis(methylenephosphonic acid). Its crystal ...