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High-Throughput Synthesis of Pillared-Layered Magnesium Tetraphosphonate Coordination Polymers: Framework Interconversions and Proton Conductivity Studies
(MDPI, www.mdpi.com/journal/inorganics, 2018-09-11)
Novel pillared-layered framework materials were synthesized by high-throughput
or microwave-assisted methodology that contain Mg2+ and the zwitterionic linker HDTMP
(hexamethylenediamine-N,N,N0,N0-tetrakis(methylenephosphonic ...
Structural variability in M2+ 2-hydroxyphosphonoacetate moderate proton conductors
(De Gruyter, 2017)
The structural variability of two series of Mg2+- and Zn2+- 2-hydroxyphosphonoacetates have been
studied in the range of 25–80 °C and 95 % relative humidity in order to correlate the structure with the
proton conductivity ...
Tuning Proton Conductivity in A Multifunctional Calcium Phosphonate Hybrid Framework
(2014-06-25)
Multi-chelating phosphonate ligands are organic linkers alternative to polycarboxylates and other ligands providing synthetic access to a number of thermally- and chemically-stable MOFs [1]. Metal phosphonates are amenable ...
Proton Conductors based on Metal Phosphonate Hybrid Materials for PEM Fuel Cells
(2014-06-25)
The necessity of energy and power generation is constantly growing. Fossils fuels are quickly becoming unsatisfactory substrates due to both their emission of pollutants and their finite expectancy. Fuel cells are one of ...