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dc.contributor.authorColodrero, Rosario M.P.
dc.contributor.authorBazaga-García, Montse
dc.contributor.authorOlivera-Pastor, Pascual 
dc.contributor.authorLosilla, E. R.
dc.contributor.authorSalcedo, Inés R.
dc.contributor.authorAranda, Miguel Ángel G.
dc.contributor.authorCabeza-Diaz, Aurelio 
dc.date.accessioned2016-06-28T07:59:46Z
dc.date.available2016-06-28T07:59:46Z
dc.date.created2016
dc.date.issued2016
dc.identifier.urihttp://hdl.handle.net/10630/11678
dc.description.abstractCrystalline metal phosphonates may offer acidic sites, structural flexibility and guest molecules (H2O, heterocyclics, etc.) which can act as proton carriers. In addition, some frameworks are also amenable for post‐synthesis modifications in order to enhance desired properties [1,2]. In this work, we present the synthesis and structural characterization of two hydroxyphosphonoacetates hybrids based on magnesium, [Mg5(O3PCHOHCOO)2(HO3PCHOHCOO)2·8H2O] [Mg5(HPAA)2(H1HPAA)2·8H2O], and zinc, [Zn6K(O3PCHOHCOO)4(OH)·6.5H2O] [Zn6K(HPAA)4(OH)·6.5H2O]. Both solids present three-dimensional frameworks and their crystal structures were solved ab initio from X-ray powder diffraction. The proton conductivity of [Zn6K(HPAA)4(OH)·6.5H2O] as well as ammonia derivatives of M(II)(HO3PCHOHCOO)·2H2O [M(II)=Zn, Mg] will be reported and discussed.es_ES
dc.description.sponsorshipUniversidad de Málaga. Campus de Excelencia Internacional Andalucía Tech. FQM-1656; MAT2013-41836-Res_ES
dc.language.isoenges_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.subjectPolímeroses_ES
dc.subjectFotopolímeroses_ES
dc.subject.otherPolymerses_ES
dc.subject.otherPolymers synthesises_ES
dc.subject.otherCoordination Polymerses_ES
dc.subject.otherMetal organic frameworkses_ES
dc.subject.otherMetal phosphonateses_ES
dc.titleStructure-properties correlations in divalent metal phosphonateses_ES
dc.typeinfo:eu-repo/semantics/conferenceObjectes_ES
dc.centroFacultad de Cienciases_ES
dc.relation.eventtitle16th International Conference “Polymers and Organic Chemistry" (POC-16)es_ES
dc.relation.eventplaceCreta (Grecia)es_ES
dc.relation.eventdate13 Junio 2016es_ES
dc.cclicenseby-nc-ndes_ES


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