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dc.contributor.authorPonce Ortiz, Rocío
dc.contributor.authorArrechea-Marcos, Iratxe
dc.contributor.authorLópez Espejo, Guzmán
dc.contributor.authorSegura, José L.
dc.contributor.authorLópez-Navarrete, Juan Teodomiro 
dc.date.accessioned2016-09-27T11:17:19Z
dc.date.available2016-09-27T11:17:19Z
dc.date.created2016
dc.date.issued2016-09-27
dc.identifier.urihttp://hdl.handle.net/10630/12101
dc.description.abstractIn the last years we have devoted some effort to the search of new high-mobility semiconductors with ambipolar performances, good processability and environmental stability. Our approach, which is one of the most widely used, consists in the combination of donor and acceptor moieties in the conjugated skeleton, which allows fine tuning of the frontier molecular orbitals. For OTFT applications, low-lying HOMOs are essential to resist air oxidation and thus increase device stability. However, if the HOMO energy is too low, the resulting barrier to hole injection may compromise the transistor performance. Thus, a delicate balance between these two effects is needed. In particular, we have combined naphthaleneimide-derived moieties as electron accepting groups with electron-rich oligothiophene fragments. In these materials, we have found that the presence of ambipolar transport in these planar molecules can be understood on the basis of three interrelated properties: (i) the absence of skeletal distortions allows closer intermolecular pi-pi stacking and enhanced intramolecular pi-conjugation, (ii) increased pi-conjugation raises the HOMO energy, which approaches the Fermi level of common used electrodes; and (iii) more planar structures translate into lower Marcus reorganization energies. However, one of the limitations of these types of semiconductors is the presence of a molecular dipole moment, which forces the molecules to pack with pairwise intermolecular interactions orienting the naphthaleneimide cores in opposite directions, decreasing in some cases molecular orbitals overlapping. In recent contributions, we have devoted our efforts to analyze the effect of molecular interactions, through chemical modifications in order to induce parallel and antiparallel molecular packing, on the electronic properties of ambipolar semiconductors.es_ES
dc.description.sponsorshipUniversidad de Málaga. Campus de Excelencia Internacional Andalucía Tech.es_ES
dc.language.isoenges_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.subjectAgujeros (Electrónica)es_ES
dc.subject.otherOrganic semiconductorses_ES
dc.subject.otherAmbipolarityes_ES
dc.subject.otherField-effect transistorses_ES
dc.subject.otherDFT calculationses_ES
dc.titleOrganic ambipolar semiconductors for TFT applicationses_ES
dc.typeinfo:eu-repo/semantics/conferenceObjectes_ES
dc.centroFacultad de Cienciases_ES
dc.relation.eventtitle6TH EUCHEMS CHEMISTRY CONGRESSes_ES
dc.relation.eventplaceSEVILLAes_ES
dc.relation.eventdate11/09/2016es_ES
dc.identifier.orcidhttp://orcid.org/0000-0002-3836-3494es_ES
dc.cclicenseby-nc-ndes_ES


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