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dc.contributor.authorValpuesta-Fernández, María 
dc.contributor.authorSánchez-Molina, María
dc.contributor.authorLucena-Serrano, Ana
dc.contributor.authorContreras-Cáceres, Rafael
dc.contributor.authorLópez-Romero, Juan Manuel 
dc.contributor.authorDíaz-Morilla, Amelia 
dc.date.accessioned2016-10-14T11:15:34Z
dc.date.available2016-10-14T11:15:34Z
dc.date.created2016
dc.date.issued2016-10-14
dc.identifier.urihttp://hdl.handle.net/10630/12227
dc.description.abstractNanostructured thin films and subsequent biofunctionalization of silicon substrates are essential for the development of biosensors devices. The formation of organic monolayers on silicon substrates via Si-C bound allows specific interactions with biomolecules and presents several advantages like greater detection sensitivity and stability against hydrolytic cleavage.1 In this sense, to control the orientation and spacing between grafted functional moieties on the surface, tripodal oligo (p-phenylene)s have become ideal anisotropic adsorbates due to their shape-persistent and selfstanding characteristics.2 On the other hand, biomolecules such as tehtahydro[3]benzazepines are well-known to contain in their structure a phenetylamine skeleton, which is also present in dopaminergic receptors and drugs, therefore these molecules have a remarkable interest in medicinal chemistry. Here we report the synthesis and characterization of several tetrahydro[3]benzazepines and tripod-shaped oligo(p-phenylene)s which were suitably functionalized for its subsequent adsorption on silicon surfaces by hydrosilylation and/or CuAAc click reaction. X-ray photoemission spectroscopy (XPS) and atomic force microscopy (AFM) analysis were also carried out to reveal the presence of the grafted molecules on the different Si surfaces.es_ES
dc.description.sponsorshipUniversidad de Málaga. Campus de Excelencia Internacional Andalucía Tech.es_ES
dc.language.isoenges_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.subjectBiomoléculases_ES
dc.subject.otherBenzazepineses_ES
dc.subject.otherTripod-shaped moleculeses_ES
dc.subject.otherSilicon surfaceses_ES
dc.subject.otherNanostructurationes_ES
dc.subject.otherFunctionalizationes_ES
dc.titleStudy and characterization of modified silicon surfaces with organic moleculeses_ES
dc.typeinfo:eu-repo/semantics/conferenceObjectes_ES
dc.centroFacultad de Cienciases_ES
dc.relation.eventtitle6th EuCheMSes_ES
dc.relation.eventplaceSevilla Spaines_ES
dc.relation.eventdate11 septiembre 2016es_ES
dc.identifier.orcidhttp://orcid.org/0000-0002-9956-5583es_ES
dc.rights.ccby-nc-sa


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