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dc.contributor.authorR.Salcedo, Inés
dc.contributor.authorBazaga-García, Montse
dc.contributor.authorColodrero, Rosario M.P.
dc.contributor.authorOlivera-Pastor, Pascual 
dc.contributor.authorLosilla, Enrique R.
dc.contributor.authorCabeza-Diaz, Aurelio 
dc.date.accessioned2017-07-10T08:21:57Z
dc.date.available2017-07-10T08:21:57Z
dc.date.created2017
dc.date.issued2017-07-10
dc.identifier.urihttp://hdl.handle.net/10630/14157
dc.description.abstractMultifunctional metal phosphonates are acidic coordination polymers (CPs) with remarkable stability and proton conducting properties owing to their structure is usually composed of extended hydrogen-bond networks that favor proton transfer pathways [1]. In this communication, three different families of proton conductors based on lanthanide nitrilotris-methylphosphonates are examined. Compounds were isolated by crystallization at room temperature at pH <0.8 in the presence of. When chloride is presented in solution two families of compounds were isolated, depending on the concentration of chloride in solution: free-chloride 1D solids with formula Ln2(H3NMP)2(H2O)4]·4.5H2O [Ln= La3+] [2] or layered chloride-containing Ln(H4NMP)(H2O)2]Cl·2H2O [Ln= La3+ - Ho3+] materials [3]. In absence of chloride, a third series of compounds was obtained. This structural versatility leads to a wide range of proton conductivity varying between 3 × 10−4 S·cm−1 and 2 × 10−3 S·cm−1 as measured at 80 °C and 95% RH.es_ES
dc.description.sponsorshipUniversidad de Málaga. Campus de Excelencia Internacional Andalucía Tech.es_ES
dc.language.isoenges_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.subjectConductores orgánicoses_ES
dc.subject.othercoordination polymerses_ES
dc.subject.othermetal phosphonateses_ES
dc.subject.otherproton conductivityes_ES
dc.subject.othersolid-state chemistryes_ES
dc.subject.othercrystal structurees_ES
dc.titleProton conductivity of lanthanide nitrilotris-methylphosphonateses_ES
dc.typeinfo:eu-repo/semantics/conferenceObjectes_ES
dc.centroFacultad de Cienciases_ES
dc.relation.eventtitleXXXVI REUNIÓN BIENAL DE LA REAL SOCIEDAD ESPAÑOLA DE QUÍMICAes_ES
dc.relation.eventplaceSitges, Españaes_ES
dc.relation.eventdate25/06/2017 - 29/06/2017es_ES
dc.cclicenseby-nc-ndes_ES


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