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dc.contributor.authorGinés Molina, María José
dc.contributor.authorLuque, Rafael
dc.contributor.authorMoreno-Tost, Ramon 
dc.contributor.authorMaireles-Torres, Pedro Jesús 
dc.date.accessioned2017-12-22T09:49:26Z
dc.date.available2017-12-22T09:49:26Z
dc.date.created2017-12-11
dc.date.issued2017-12-22
dc.identifier.urihttps://hdl.handle.net/10630/14977
dc.description.abstractIsosorbide is one of the most promising products derived from sorbitol. It has already found many applications, mainly in the polymer industry and medicine, such as isosorbide polycarbonate1 (DURABIO®) and isosorbide nitrates as vasodilator for angina pectoris2. The methylation of the two hydroxyl groups of isosorbide molecule gives rise to the formation of dimethyl isosorbide (DMI), which is a high boiling solvent (235ºC), used in skin care formulations because of its solubilising capacity and performance enhancing of many different topical skin actives3. Currently, DMI synthesis implies the use of methyl halides or dimethyl sulfate. A safer and more environmental benign approach has been proposed by Tundo et al4 by employing dimethylcarbonate (DMC) as both reactant and solvent in the presence of sodium methoxide. In the present work, the synthesis of DMI in an excess of DMC by using a MgAl mixed oxides (MgAlOx), as heterogeneous catalyst, under mild reaction conditions, is proposed.en_US
dc.description.sponsorshipUniversidad de Málaga. Campus de Excelencia Internacional Andalucía Tech. Proyecto Plan Nacional CTQ2015-64226-C3-3-R Fondos FEDERen_US
dc.language.isoengen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectQuímica inorgánica - Congresosen_US
dc.subject.otherBiomassen_US
dc.subject.otherDimethylisosorbideen_US
dc.subject.otherSorbitolen_US
dc.subject.otherDimethylcarbonateen_US
dc.subject.otherHeterogeneous catalysisen_US
dc.titleGreen approach to the Isosorbide Conversion into Dimethyl isosorbideen_US
dc.typeinfo:eu-repo/semantics/otheren_US
dc.centroFacultad de Cienciasen_US
dc.relation.eventtitle4th International Congress on Catalysis for Biorefineriesen_US
dc.relation.eventplaceLyon (Francia)en_US
dc.relation.eventdate11-diciembre-2017en_US


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