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dc.contributor.authorCollado, Daniel 
dc.date.accessioned2018-09-19T08:48:47Z
dc.date.available2018-09-19T08:48:47Z
dc.date.created2018
dc.date.issued2018-09-19
dc.identifier.urihttps://hdl.handle.net/10630/16484
dc.description.abstractSquaraines is an important part of the cyanine family which have high extinction coefficients, sharp absorption bands, and intense fluorescence spectra in the red and near infrared region in solution.[1] The unique electronic structure and such optical characteristics have made squaraines very attractive for many applications, such as chemosensors, organic solar cells, optical recording media, electro-luminescence diodes, and nonlinear optical devices.[2] 2,3,3-Trimethylindolenine-based squaraines are prepared by the condensation of the heterocyclic quaternary ammonium salts with squaric acid in high boiling point alcohols such as butanol, often in a mixture with aromatic hydrocarbons such as toluene or benzene in order to azeotropically remove the water formed in the condensation reaction (Dean−Stark apparatus).[3] In this communication, we present a series of aminonaphthalimide–squaraine dyads (1) and (2) that shown squaraine fluorescence sensitization [3]. This was observed upon one- and two-photon excitation of naphthalimide subunits, which extends the application range of the investigated bichromophoric dyads in terms of accessible excitation wavelengths. In comparison with the direct excitation of the squarine chromophore, the two-photon absorption cross-section  of the dyad (1) is significantly incremented by the presence of the aminonaphthalimide donor. Figure 1 The applicability of the new dyad in the one- and two-photon excitation mode was demonstrated in solution and in a proof-of-principle approach in the fluorescence imaging of HeLa cells (Figure 1). Acknowledgments: The present study has been supported by MINECO CTQ2016-75870P; by Andalusian Regional Ministry Health (grants: PI-0250-2016); by the European Regional Development Fund (ERDF) and “Plan Propio Universidad de Málaga” (UMA-Andalucía-TECH).en_US
dc.description.sponsorshipUniversidad de Málaga. Campus de Excelencia Internacional Andalucía Tech.en_US
dc.language.isoengen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectFotoquímicaen_US
dc.subjectQuimisorciónen_US
dc.subject.otherSquaraineen_US
dc.titleAminonaphtamiline-squaraine dyad: photophysical properties and bioimaging applicationen_US
dc.typeinfo:eu-repo/semantics/conferenceObjecten_US
dc.centroFacultad de Cienciasen_US
dc.relation.eventtitleVI Jornadas Ibéricas de Fotoquímica (6'JIF)en_US
dc.relation.eventplaceAveiro, Portugalen_US
dc.relation.eventdate11/09/2018en_US
dc.rights.ccAttribution-NonCommercial-NoDerivatives 4.0 Internacional*


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Attribution-NonCommercial-NoDerivatives 4.0 Internacional
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