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Kinetic study of methanol dehydration to DME on Zr-loaded P-containing mesoporous activated carbon catalyst
dc.contributor.author | Palomo-Jiménez, José | |
dc.contributor.author | Rodríguez-Cano, Miguel A | |
dc.contributor.author | Rodríguez-Mirasol, José | |
dc.contributor.author | Cordero-Alcántara, Tomás | |
dc.date.accessioned | 2019-06-28T06:36:08Z | |
dc.date.available | 2019-06-28T06:36:08Z | |
dc.date.created | 2019-06 | |
dc.date.issued | 2019-06-28 | |
dc.identifier.uri | https://hdl.handle.net/10630/17909 | |
dc.description.abstract | The selective methanol dehydration to DME using a Zr-loaded P-containing activated carbon catalyst have been studied. The activated carbon was prepared by chemical activation of olive stones with phosphoric acid. Then, the resulting activated carbon was loaded with a 5 % of Zr by incipient wetness impregnation. A kinetic study for the selective methanol dehydration to DME was carried out and the corresponding kinetic and thermodynamic parameters were calculated. Three reaction mechanism were proposed. A Langmuir-Hinshelwood like mechanism was the one that better reproduced the experimental data. | en_US |
dc.description.sponsorship | Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech | en_US |
dc.language.iso | eng | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | Metanol | en_US |
dc.subject | Carbón activado | en_US |
dc.subject | Dimetil-eter (DME) | en_US |
dc.subject.other | Mesoporous carbon | en_US |
dc.subject.other | Heterogeneous catalysis | en_US |
dc.subject.other | Methanol dehydration | en_US |
dc.subject.other | dimethyl ether | en_US |
dc.subject.other | Phosphorus functionalization | en_US |
dc.subject.other | Zirconium | en_US |
dc.title | Kinetic study of methanol dehydration to DME on Zr-loaded P-containing mesoporous activated carbon catalyst | en_US |
dc.type | info:eu-repo/semantics/other | en_US |
dc.centro | Escuela de Ingenierías Industriales | en_US |
dc.relation.eventtitle | ANQUE-ICCE-CIBIQ 2019 | en_US |
dc.relation.eventplace | Santander (España) | en_US |
dc.relation.eventdate | 06/2019 | en_US |