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dc.contributor.authorCasado-Cordon, Juan 
dc.contributor.authorZafra, Jose Luis
dc.contributor.authorCasanova, David
dc.contributor.authorZhu, Xiaozhang
dc.contributor.authorMedina Rivero, Samara
dc.date.accessioned2019-07-05T09:19:06Z
dc.date.available2019-07-05T09:19:06Z
dc.date.created2019
dc.date.issued2019-07-05
dc.identifier.urihttps://hdl.handle.net/10630/17950
dc.description.abstractSince -conjugated organic molecules were probed as potential semiconducting materials, suitable for replacing the widely used silicon technologies, their structural, optical and conductive properties have been under study to improve their application in organic electronics and to make possible their ad hoc synthesis. In this sense, the modification of the -electron delocalization path is one of the available tools to tune the properties of the molecules to obtain the desired characteristics for the fabrication of these devices. One of the parameters employed to tailor -conjugated organic molecules for organic electronics is the diradical character. A progressive change in the diradical contribution to the ground electronic state structure can tune some of the main system features, highlighting the HOMO-LUMO energy gap and the aggregation mode. The main drawback of this approach is the loss of chemical stability when increasing the diradical character of these molecules. On the other hand, the -electron delocalization can be interrupted introducing a perpendicularly conjugated path. The competition of these two cross-conjugated patterns leads to a new 2-dimensional delocalization scenario that changes the electronic properties of the studied materials. In this project, we present a stable quinoidal quaterthiophene diradical that possess outstanding stability and conductivity properties. [1] The combination of the diradical character together with the possibility to delocalize the electron density through two different perpendicular paths explain its exceptional behavior in comparison with the other members of the series, or with its linearly conjugated analogues. The balance between these two properties has been evaluated through UV-Vis-NIR electronic spectroscopy and Raman and IR vibrational spectroscopy in the neutral and charged forms of the target molecule and similar non-cross-conjugated samples.en_US
dc.description.sponsorshipUniversidad de Málaga. Campus de Excelencia Internacional Andalucía Tech.en_US
dc.language.isoengen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectEspectroscopia Ramanen_US
dc.subjectCongresos y conferenciasen_US
dc.subject.otherRaman spectroscopyen_US
dc.titleRaman spectroscopy as a versatile tool to study organic biradicalsen_US
dc.typeinfo:eu-repo/semantics/conferenceObjecten_US
dc.centroFacultad de Cienciasen_US
dc.relation.eventtitle10 International Conference on Materials for Advanced Technologies, ICMATen_US
dc.relation.eventplaceSingaporeen_US
dc.relation.eventdate23-26 Junio 2019en_US
dc.rights.ccAttribution-NonCommercial-NoDerivatives 4.0 Internacional*


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