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dc.contributor.authorCasado-Cordon, Juan 
dc.date.accessioned2019-07-17T11:33:34Z
dc.date.available2019-07-17T11:33:34Z
dc.date.created2019
dc.date.issued2019-07-17
dc.identifier.urihttps://hdl.handle.net/10630/18068
dc.descriptionResumen de la comunicación oral seleccionadaen_US
dc.description.abstractDiradicals are beautiful chemical objects where the more basic and intricate aspects of the chemical bonding are revealed.1 Not this being important enough, nowadays, diradical-based substrates are becoming very appealing for new organic electronic applications. We focus here in conjugated organic diradicals formed by competition between non-aromatic quinoidal structures and their canonical aromatic forms. How this quinoidal(closed-shell)-vs-aromatic(open-shell) energetic balance producing the diradical is affected by several situations has been our objective in the last few years.2 Now, we focusses on how the properties of diradicals are influenced when several diradical canonical forms are available in such a way that create a 2D (i.e., bidimensional) electron delocalization surface in which the diradical substructures are in cross-conjugation mode producing the curious effect of diradical confinement.3 Herein, the diradical molecular properties of compound 1 in Figure 1 will be discussed in connection with 2D delocalization, cross-conjugation and surface confinement. 1. Rajca, A., Chem. Rev., 1994, 94, 871; Abe, M., Chem. Rev. 2013, 113, 7011. 2. Zeng, Z.; X. Shi, L.; Chi, C.; Casado, J.; Wu, J. Chem. Soc. Rev. 2015, 44, 6578. 3. Yuan, D.; Huang, D.; Medina Rivero, S.; Carreras, A.; Zhang, C.; Zou, Y.; Jiao, X.; McNeill, C.R.; Zhu, X.; Di, C.; Zhu, D.; Casanova, D.; Casado, J. CHEM, 2019, accepted.en_US
dc.description.sponsorshipUniversidad de Málaga. Campus de Excelencia Internacional Andalucía Tech.en_US
dc.language.isoengen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectCompuestos aromáticosen_US
dc.subject.otherDiradicalen_US
dc.title2D-Delocalized vs Confined Diradicalsen_US
dc.typeinfo:eu-repo/semantics/conferenceObjecten_US
dc.centroFacultad de Cienciasen_US
dc.relation.eventtitleInternational Symposium on Novel Aromatic Compounds, ISNA-18en_US
dc.relation.eventplaceSapporo, Ohkaido, Japónen_US
dc.relation.eventdate21-26 juio 2019en_US
dc.rights.ccAttribution-NonCommercial-NoDerivatives 4.0 Internacional*


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Attribution-NonCommercial-NoDerivatives 4.0 Internacional
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