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dc.contributor.authorHarbuzaru, Alexandra
dc.contributor.authorPonce-Ortiz, Rocío 
dc.contributor.authorRuíz-Delgado, María del Carmen
dc.contributor.authorYang, Kun
dc.contributor.authorGuo, Xugang
dc.date.accessioned2020-01-29T12:30:02Z
dc.date.available2020-01-29T12:30:02Z
dc.date.created2020
dc.date.issued2020-01-29
dc.identifier.urihttps://hdl.handle.net/10630/19234
dc.description.abstractOrganic diradicals are molecules containing two unpaired electrons, which are usually highly reactive.1-2 Although these organic diradicals present a wide range of potential applications, their air stability still remains as a major obstacle.3 In order to overcome this, new organic diradicals based on quinoidal oligothiophenes-derivatives (QOT) have been synthesized, i.e. BTICN, ISOCN and QTICN (see Figure 1). These new molecules present high stability and electrical conductivity, which have been achieved by employing imide-bridged fused molecular frameworks. The combination of strong electron-withdrawing imide with tetracyano groups in the conjugated skeletons also enabled extremely deeply aligned LUMO levels and large diradical character assisted by cross-conjugation.4 Here we use different experimental techniques and DFT calculations to provide new insights into the electron conduction mechanism of QOT diradicaloids, in order to demonstrate the great potential of fused quinoidal oligothiophene imides in developing stable organic diradicals and high-performance doping-free n-type conductive materials.en_US
dc.description.sponsorshipUniversidad de Málaga. Campus de Excelencia Internacional Andalucía Tech.en_US
dc.language.isoengen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectEspectroscopía Ramanen_US
dc.subject.otherRaman spectroscopyen_US
dc.subject.otherDiradicalsen_US
dc.subject.otherQuinoid systemsen_US
dc.titleFused Quinoidal Oligothiophenes Imides with High Electrical Conductivityen_US
dc.typeinfo:eu-repo/semantics/conferenceObjecten_US
dc.centroFacultad de Cienciasen_US
dc.relation.eventtitle11th Symposium on Computing π-conjugated Compoundsen_US
dc.relation.eventplaceZagreben_US
dc.relation.eventdate30/01/2020en_US
dc.rights.ccAttribution-NonCommercial-NoDerivatives 4.0 Internacional*


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