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dc.contributor.authorMaranescu, Bianca
dc.contributor.authorVisa, Aurelia
dc.contributor.authorIlia, Gheorghe
dc.contributor.authorSimon, Zeno
dc.contributor.authorDemadis, Konstantinos D.
dc.contributor.authorPérez-Colodrero, Rosario Mercedes 
dc.contributor.authorCabeza-Díaz, Aurelio 
dc.contributor.authorVallcorba, Oriol
dc.contributor.authorRius, Jordi
dc.contributor.authorChoquesillo-Lazarte, Duane
dc.date.accessioned2021-03-04T09:34:20Z
dc.date.available2021-03-04T09:34:20Z
dc.date.created2021
dc.date.issued2014-04-11
dc.identifier.citationJournal of Coordination Chemistry, 67:9, 1562-1572es_ES
dc.identifier.urihttps://hdl.handle.net/10630/21018
dc.description.abstractWe report the synthesis, physicochemical characterization, and crystal structure of Cu-SP (SP = styrylphosphonic acid, H2O3PCH=CH2(C6H5)), the first reported example of a metal derivative of SP. The starting SP acid was fully characterized by X-ray single-crystal diffractometry, elemental analysis (C and H), 31P-NMR, 13C-NMR, 1H-NMR, HPLC, UV–vis, MS, TG, and FT-IR spectroscopy. The copper(II) derivative was synthesized and characterized by DTA-TG and FT-IR, and also its structure was determined from powder data. The crystal structure was refined by the Rietveld method. The crystal structure of Cu-SP shows a layered 2-D architecture, where the organic moieties are pointed toward the interlamellar space. The inorganic layers are composed of Cu2+ dimers, where the coordination geometry of Cu2+ can be described as distorted trigonal bipyramid. The three coplanar oxygens (O2, O3, and O3) have bond distances of 2.165(9), 1.982(9), and 2.103(11) Å, respectively. The bond lengths for the apical oxygens (O1 and O2) are 1.908(13) and 1.996(11) Å, respectively.es_ES
dc.description.sponsorshipProyecto nacional MAT2010-15175es_ES
dc.language.isoenges_ES
dc.publisherTaylor & Francises_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.subjectQuímica inorgánicaes_ES
dc.subject.otherStyrylphosphonic acides_ES
dc.subject.otherMetal phosphonateses_ES
dc.subject.otherCopperses_ES
dc.subject.otherMOFes_ES
dc.subject.otherLayered compoundses_ES
dc.subject.otherUnsaturated phosphonatees_ES
dc.titleSynthesis and structural characterization of 2-D layered copper(II) styrylphosphonate coordination polymerses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.centroFacultad de Cienciases_ES
dc.identifier.doi10.1080/00958972.2014.928289
dc.type.hasVersioninfo:eu-repo/semantics/publishedVersiones_ES


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