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dc.contributor.authorAlonso-Navarro, Matías J.
dc.contributor.authorHarbuzaru, Alexandra
dc.contributor.authorMartínez-Fernández, Marcos
dc.contributor.authorPérez Camero, Paula
dc.contributor.authorLópez-Navarrete, Juan Teodomiro 
dc.contributor.authorRamos, M. Mar
dc.contributor.authorPonce-Ortiz, Rocío 
dc.contributor.authorSegura, José L.
dc.date.accessioned2022-05-03T06:48:45Z
dc.date.available2022-05-03T06:48:45Z
dc.date.issued2021-06-02
dc.identifier.citationAlonso-Navarro, Matías J. Harbuzaru, Alexandra Martínez-Fernández, Marcos Pérez Camero, Paula López-Navarrete, Juan Teodomiro Ramos, M. Mar Ponce-Ortiz, Rocio José L., Segura. Synthesis and electronic properties of nitrogen-doped π-extended polycyclic aromatic dicarboximides with multiple redox processes. J. Mater. Chem. C, 2021,9, 7936-7949. https://doi.org/10.1039/D1TC01239Hes_ES
dc.identifier.urihttps://hdl.handle.net/10630/24013
dc.description.abstractIn this work, a series of nitrogen-doped polycyclic aromatic mono and dicarboximides was designed, and their synthesis is reported by an innovative synthetic procedure that avoids metal-based cross-coupling reactions. A combined theoretical, electrochemical, optical spectroscopy and material characterization study allows the investigation of the interplay of different effects such as (i) the type of solubilizing chain, (ii) the all-acceptor vs. donor–acceptor nature of the novel systems, and (iii) the molecular ordering, on the ability to stabilize multiple charges and on the OTFT device response characteristics. The amphoteric redox behavior of some of the novel systems allow to obtain ambipolar mobilities while the electron mobility values of the three all-acceptor systems can be rationalized in terms of supramolecular aggregation and enhanced film-forming ability.es_ES
dc.description.sponsorshipFunding for open access charge: Universidad de Málaga. This work was financially supported by MICINN (PID2019-106268GB-C33) and the UCM (INV.GR.00.1819.10759). MJAN gratefully acknowledges Universidad Rey Juan Carlos for a predoctoral contract. The university of Ma´laga acknowledges support from Junta de Andalucı´a (projects UMA18-FEDERJA080 and P18-FR-4559) and MICINN (PID2019-110305GB-I00). RPO and AH also thank the Research Central Services (SCAI) of the University of Ma´laga and especially the Vibrational Spectroscopy Laboratory.es_ES
dc.language.isoenges_ES
dc.publisherRoyal Society of chemistryes_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/*
dc.subjectEspectroscopíaes_ES
dc.subject.otherOptical spectroscopyes_ES
dc.subject.otherRedox processeses_ES
dc.titleSynthesis and electronic properties of nitrogen-doped π-extended polycyclic aromatic dicarboximides with multiple redox processeses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.identifier.doihttps://doi.org/10.1039/D1TC01239H
dc.rights.ccAtribución-NoComercial 4.0 Internacional*


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