Listar IQ - Artículos por centro "Facultad de Ciencias"
Mostrando ítems 1-20 de 35
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A Kinetic Model Considering Catalyst Deactivation for Methanol-to-Dimethyl Ether on a Biomass-Derived Zr/P-Carbon Catalyst
(IOAP-MDPI, 2022-01-13)A Zr-loaded P-containing biomass-derived activated carbon (ACPZr) has been tested for methanol dehydration between 450 and 550 °C. At earlier stages, methanol conversion was complete, and the reaction product was mainly ... -
Acid leaching of LiCoO2 enhanced by reducing agent. Model formulation and validation.
(Elsevier, 2021-08-25)In this work, a model has been formulated to describe the complex process of LiCoO2 leaching through the participation of competing reactions in acid media including the effect of H2O2 as reducing agent. The model presented ... -
Activation of electrospun lignin-based carbon fibers and their performance as self-standing supercapacitor electrodes
(2020-02-17)The production and activation of self-standing carbon electrodes from electrospun lignin fibers was analyzed in this work. Carbon microfibers were prepared at 900 °C from air-stabilized spun cloths by direct carbonization ... -
Assessment of Agricultural Residue to Produce Activated Carbon-Supported Nickel Catalysts and Hydrogen Rich Gas.
(MDPI, 2023-05-08)The aim of this study was to synthesize chemically activated carbons from different agricultural residues, i.e., pistachio shell (PS), bitter orange peel (OP), and saffron petal (SP), and subsequently to use them as supports ... -
Bi-reforming of Biogas for Hydrogen Production with Sulfur-Resistant Multimetallic Catalyst
(Wiley, 2023)A multimetallic sample, NiCeSnRh/Al2O3, was tested in methane reforming with a CH4:H2O:CO2 molar ratio equal to 3:2:1. A very stable methane conversion with the time-on-stream was achieved during 20 h. Dimethyl sulfide ... -
Biobased Vanillin Production by Oxidative Depolymerization of Kraft Lignin on a Nitrogen- and Phosphorus-Functionalized Activated Carbon Catalyst
(ACS, 2024-04-04)The sustainable production of vanillin from the oxidative depolymerization of lignin was evaluated. Vanillin was produced from Kraft lignin using heterogeneous catalysts based on activated carbons prepared by chemical ... -
Biomass-derived activated carbon catalysts for the direct dimethyl ether synthesis from syngas
(Elsevier, 2024-02-27)The direct DME synthesis from syngas was studied by using activated carbon-based bifunctional catalytic beds. Two kinds of activated carbons, prepared by physical (by CO2 partial gasification) and chemical (with phosphoric ... -
Carbon-based materials as Catalyst Supports for Fischer–Tropsch Synthesis: a review
(Frontiers, 2021-02-04)The use of carbon-based materials as catalyst supports for Fischer–Tropsch synthesis (FTS) is thoroughly reviewed. The main factors to consider when using a carbonaceous catalyst support for FTS are first discussed. Then, ... -
Carbon/H-ZSM-5 composites as supports for bi-functional Fischer-Tropsch synthesis catalysts
(Royal Society of Chemistry, 2016)Mesoporous H-ZSM-5–carbon composites, prepared via tetrapropylammonium hydroxide (TPAOH) post treatment of H-ZSM-5 followed by deposition of pyrolytic carbon, have been used as the support for the preparation of Co-based ... -
Chemical reduction of nitrate by zero-valent iron: Shrinking-Core versus Surface Kinetics Models
(MDPI, 2020-02-12)Zero valent iron (ZVI) is being used in permeable reactive barriers (PRB) for the removal of oxidant contaminants, from nitrate to chlorinated organics. A sound design of these barriers requires a good understanding of ... -
CO2-SR technology using NiBa unsupported catalyst. Isotopic study of cyclic process of CO2 storage and in situ regeneration with CH4
(Elsevier, 2023)The unsupported NiBa catalyst has been used in the CO2-SR (CO2 Storage and in situ Regeneration with CH4) cyclic technology, which allows the use of CO2 from combustion and CH4 from biogas in order to produce enriched ... -
Comparison of Cu-CHA-zeolites in the hybrid NSR-SCR catalytic system for NOx abatement in mobile sources
(MDPI, 2023-03-10)DeNOx activity in a NSR–SCR hybrid system of two copper-containing chabazite-type zeolitic catalysts was addressed. A Pt-Ba-K/Al2O3 model catalyst was used as the NSR (NOx storage and reduction) catalyst. For the SCR ... -
Deactivation of a Biomass-Derived Zirconium-Doped Phosphorus-Containing Carbon Catalyst in the Production of Dimethyl Ether from Methanol Dehydration
(ACS, 2021-08-31)Dehydration of methanol to produce dimethyl ether (DME) was studied at relatively high temperatures (400–600 °C) on biomass-derived phosphorus-containing carbon impregnated with a zirconium salt. Highly thermally stable ... -
Effect of heating rate and H3PO4 as catalyst on the pyrolysis of agricultural residues
(Elsevier, 2022-11)This study reports the effect of heating rate and the addition of H3PO4 on the pyrolysis of three representative agricultural wastes of different lignocellulosic composition, namely pistachio shell, bitter orange peel, and ... -
Effect of Nb as dopant of hydrotalcite catalysts during the ethanol condensation to optimize n-Butanol production
(Elsevier, 2024)The present study optimizes Cu-supported catalysts on hydrotalcite for the synthesis of n-butanol whose interest is in its use as biofuel, due to its superior performance in comparison with other short-chain alcohols. ... -
Efficient methanol dehydration to DME and light hydrocarbons by submicrometric ZrO2-ZSM-5 fibrillar catalysts with a shell-like structure
(Elsevier, 2022-01-20)Zeolites are widely used in many applications, such as catalysis and adsorption processes. The use of these materials in a nanometric size would be of great interest for these applications, due to the better performance ... -
Hierarchical porous carbons by liquid phase impregnation of zeolite templates with lignin solution
(ELSEVIER, 2014-05-09)Templated carbon materials (TCs) with hierarchical pore structure were obtained by liquid phase impreg- nation of different zeolite templates using Alcell lignin solutions as carbon precursor. The effect of synthesis ... -
Highly porous and conductive functional carbon fibers from electrospun phosphorus-containing lignin fibers
(Francisco J. García-Mateos, Juana M. Rosas, Ramiro Ruiz-Rosas, José Rodríguez-Mirasol, Tomás Cordero, Highly porous and conductive functional carbon fibers from electrospun phosphorus-containing lignin fibers, Carbon, Volume 200, 2022, Pages 134-148, ISSN 0008-6223, https://doi.org/10.1016/j.carbon.2022.08.050, 2022-11-05)Functional carbon fibers were prepared by carbonization of thermostabilized electrospun lignin-fibers at 500–900 °C followed by a high temperature thermal treatment at 1200–1600 °C. The effect of the preparation temperature ... -
Hydrometallurgical extraction of Li and Co from LiCoO2 particles–Experimental and Modeling
(MDPI, 2020-09-13)The use of lithium-ion batteries as energy storage in portable electronics and electric vehicles is increasing rapidly, which involves the consequent increase of battery waste. Hence, the development of reusing and recycling ... -
Incentivizing Student Participation in QAS Questionnaires: An Evaluation of a Guaranteed Prize System at the University of Malaga.
(MPDI, 2024-02-21)This paper investigates the effects of a guaranteed prize incentive, in the form of an extra score, on student engagement in the quality assurance system (QAS) questionnaires employed for evaluating teaching performance ...