Listar IQ - Artículos por tipo "info:eu-repo/semantics/publishedVersion"
Mostrando ítems 1-20 de 40
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A comparison of batch and semi-batch reactors for leaching battery cathodes (LiCoO2) under controlled addition of HCl and H2O2
Cerrillo-González, María del Mar; Villén-Guzmán, María Dolores
; Rivas-Bascon, Alvaro; Rodríguez-Maroto, José Miguel; Paz-García, Juan Manuel (Elsevier, 2024-08)
Recovery of cobalt and lithium from end-of-life Li-ion battery wastes have been evaluated in batch and semi- batch leaching systems. In this preliminary study, HCl and H2O2 were used as leaching and reducing agents, re ... -
A Kinetic Model Considering Catalyst Deactivation for Methanol-to-Dimethyl Ether on a Biomass-Derived Zr/P-Carbon Catalyst
Torres-Liñán, Javier; Ruiz-Rosas, Ramiro Rafael; Rosas-Martínez, Juana María; Rodríguez-Mirasol, José; Cordero-Alcántara, Tomás (IOAP-MDPI, 2022-01-13)
A Zr-loaded P-containing biomass-derived activated carbon (ACPZr) has been tested for methanol dehydration between 450 and 550 °C. At earlier stages, methanol conversion was complete, and the reaction product was mainly ... -
A new versatile x–y–z electrospinning equipment for nanofiber synthesis in both far and near field.
Calzado-Delgado, María del Mar; Guerrero-Pérez, María Olga; Yeung, King (Nature, 2022-03-22)
This work describes a versatile electrospinning equipment with rapid, independent, and precise x–y–z movements for large-area depositions of electrospun fibers, direct writing or assembly of fibers into sub-millimeter and ... -
A solid-state integrated photo-supercapacitor based on ZnO nanorod arrays decorated with Ag2S quantum dots as photoanode and PEDOT charge storage counter-electrode.
Solis Cortes, Daniel; Navarrete-Astorga, Elena; Sherebler, Ricardo; Peinado-Pérez, Juan José; Martín-Jiménez, Francisco de Paula; Ramos-Barrado, José Ramón; Dalchiele, Enrique A.[et al.] (Royal Society of Chemistry, 2020)
A planar solid-state photocapacitor with two electrodes has been prepared for the first time using a passivated film of ZnS with Ag2S quantum dots deposited on ZnO nanorods, which were electrochemically grown on ZnO seed ... -
Acid leaching of LiCoO2 enhanced by reducing agent. Model formulation and validation.
Cerrillo-González, María del Mar; Villén-Guzmán, María Dolores; Vereda-Alonso, Carlos; Rodríguez-Maroto, José Miguel; Paz-García, Juan Manuel (Elsevier, 2021-08-25)
In this work, a model has been formulated to describe the complex process of LiCoO2 leaching through the participation of competing reactions in acid media including the effect of H2O2 as reducing agent. The model presented ... -
Assessment of Agricultural Residue to Produce Activated Carbon-Supported Nickel Catalysts and Hydrogen Rich Gas.
Hosseinzaei, Behnam; Hadianfard, Mohammad Jafar; Esmaeilzadeh, Feridun; Recio-Ruiz, María del Carmen; Ruiz-Rosas, Ramiro Rafael; Rosas-Martínez, Juana María; Rodríguez-Mirasol, José; Cordero-Alcántara, Tomás[et al.] (MDPI, 2023-05-08)
The aim of this study was to synthesize chemically activated carbons from different agricultural residues, i.e., pistachio shell (PS), bitter orange peel (OP), and saffron petal (SP), and subsequently to use them as supports ... -
Bi-reforming of Biogas for Hydrogen Production with Sulfur-Resistant Multimetallic Catalyst
Poggio-Fraccari, Eduardo; Mariño, Fernando; Herrera-Delgado, María Concepción; Larrubia-Vargas, María Ángeles; Alemany-Arrebola, Luis José (Wiley, 2023)
A multimetallic sample, NiCeSnRh/Al2O3, was tested in methane reforming with a CH4:H2O:CO2 molar ratio equal to 3:2:1. A very stable methane conversion with the time-on-stream was achieved during 20 h. Dimethyl sulfide ... -
Biobased Vanillin Production by Oxidative Depolymerization of Kraft Lignin on a Nitrogen- and Phosphorus-Functionalized Activated Carbon Catalyst
García-Rollán, Miguel; Rivas-Márquez, María Nerea; Bertran-Llorens, Salvador; Deuss, Peter J.; Ruiz-Rosas, Ramiro Rafael; Rosas-Martínez, Juana María; Rodríguez-Mirasol, José; Cordero-Alcántara, Tomás[et al.] (ACS, 2024-04-04)
The sustainable production of vanillin from the oxidative depolymerization of lignin was evaluated. Vanillin was produced from Kraft lignin using heterogeneous catalysts based on activated carbons prepared by chemical ... -
Biomass-derived activated carbon catalysts for the direct dimethyl ether synthesis from syngas
Palomo, José; Rodríguez-Cano, Miguel Ángel; Rodríguez-Mirasol, José; Cordero-Alcántara, Tomás (Elsevier, 2024-02-27)
The direct DME synthesis from syngas was studied by using activated carbon-based bifunctional catalytic beds. Two kinds of activated carbons, prepared by physical (by CO2 partial gasification) and chemical (with phosphoric ... -
Carbon-based materials as Catalyst Supports for Fischer–Tropsch Synthesis: a review
Valero-Romero, María José; Rodríguez-Cano, Miguel Ángel; Palomo, José; Rodríguez-Mirasol, José; Cordero-Alcántara, Tomás (Frontiers, 2021-02-04)
The use of carbon-based materials as catalyst supports for Fischer–Tropsch synthesis (FTS) is thoroughly reviewed. The main factors to consider when using a carbonaceous catalyst support for FTS are first discussed. Then, ... -
Carbon-supported VPO catalysts with fibrous structure: A new family of catalysts for partial oxidation reactions
Guerrero-Pérez, María Olga; Berenguer-Betrián, Raúl; Ford, Michael; Wachs, Israel E. (Elsevier, 2023-07-15)
The present contribution describes the synthesis of a carbon supported VPO catalyst with a fibrous structure. The synthesis method is simple, low-cost, scalable and reproducible that allows the formation of the bulk mixed ... -
Carbon/H-ZSM-5 composites as supports for bi-functional Fischer-Tropsch synthesis catalysts
Valero-Romero, María José; Sartipi, Sina; Sun, Xiaohui; Rodríguez-Mirasol, José; Cordero-Alcántara, Tomás; Kapteijn, Freek; Gascón, Jorge[et al.] (Royal Society of Chemistry, 2016)
Mesoporous H-ZSM-5–carbon composites, prepared via tetrapropylammonium hydroxide (TPAOH) post treatment of H-ZSM-5 followed by deposition of pyrolytic carbon, have been used as the support for the preparation of Co-based ... -
Chemical reduction of nitrate by zero-valent iron: Shrinking-Core versus Surface Kinetics Models
Villén-Guzmán, María Dolores; Paz-García, Juan Manuel; Arhoun, Brahim; Cerrillo-González, María del Mar; Rodríguez-Maroto, José Miguel; Vereda-Alonso, Carlos; Gómez-Lahoz, César[et al.] (MDPI, 2020-02-12)
Zero valent iron (ZVI) is being used in permeable reactive barriers (PRB) for the removal of oxidant contaminants, from nitrate to chlorinated organics. A sound design of these barriers requires a good understanding of ... -
CO2-SR technology using NiBa unsupported catalyst. Isotopic study of cyclic process of CO2 storage and in situ regeneration with CH4
Molina-Ramírez, Sergio; Peltzer, D.; Cortés-Reyes, Marina; Herrera-Delgado, María Concepción; Larrubia-Vargas, María Ángeles; Cornaglia, L.; Alemany-Arrebola, Luis José[et al.] (Elsevier, 2023)
The unsupported NiBa catalyst has been used in the CO2-SR (CO2 Storage and in situ Regeneration with CH4) cyclic technology, which allows the use of CO2 from combustion and CH4 from biogas in order to produce enriched ... -
Combined Operando XANES and NMR and ESR Spectroscopies for the Determination of VPO Dynamic States.
Guerrero-Pérez, María Olga; Lapina, Olga B.; Rasmussen, Soren B.; Bañares, Miguel Ángel (Springer, 2023-05-29)
Nanoscaled-VPO (vanadium phosphate oxide) catalysts have been prepared on an alumina support with the objective of obtaining crystallites of the active phase with a high surface-to-volume ratio. Since the catalysed reaction ... -
Comparison of Cu-CHA-zeolites in the hybrid NSR-SCR catalytic system for NOx abatement in mobile sources
Molina-Ramírez, Sergio; Cortés-Reyes, Marina; Herrera-Delgado, María Concepción; Larrubia-Vargas, María Ángeles; Alemany-Arrebola, Luis José (MDPI, 2023-03-10)
DeNOx activity in a NSR–SCR hybrid system of two copper-containing chabazite-type zeolitic catalysts was addressed. A Pt-Ba-K/Al2O3 model catalyst was used as the NSR (NOx storage and reduction) catalyst. For the SCR ... -
Dissolvable Topical Formulations for Burst and Constant Delivery of Vitamin C
Calzado-Delgado, María del Mar; Guerrero-Pérez, María Olga; Yeung, King (American Chemical Society, 2023-03-27)
Healthy skin has a high vitamin C concentration that protects against ultraviolet (UV)-induced damage, promotes wound healing, and lowers cancer risk. The present contribution describes two drug delivery systems for topical ... -
Effect of heating rate and H3PO4 as catalyst on the pyrolysis of agricultural residues
Hosseinzaei, Behnam; Hadianfard, Mohammad Jafar; Ruiz-Rosas, Ramiro Rafael; Rosas-Martínez, Juana María; Rodríguez-Mirasol, José; Cordero-Alcántara, Tomás[et al.] (Elsevier, 2022-11)
This study reports the effect of heating rate and the addition of H3PO4 on the pyrolysis of three representative agricultural wastes of different lignocellulosic composition, namely pistachio shell, bitter orange peel, and ... -
Effect of hydroxylammonium chloride as a reductant for hydrochloric acid leaching of valuable metals from discarded lithium-ion batteries
Cerrillo-González, María del Mar; Villén-Guzmán, María Dolores; Arhoun, Brahim; Gómez-Lahoz, César; Vereda-Alonso, Carlos (Elsevier, 2024-06)
The use of hydroxylammonium chloride as a reducing agent is proposed to enhance the acid leaching of cathode material from spent lithium-ion batteries. The current study was conducted using real waste from scooter ... -
Effect of Nb as dopant of hydrotalcite catalysts during the ethanol condensation to optimize n-Butanol production
Valdivieso-Vera, Daniel Alejandro; Flores-Escamilla, Gerardo Antonio; Cano-Gómez, José Julián; Barroso-Martín, Isabel; Rodríguez-Castellón, Enrique; Santos-López, Iván Alonso; Guerrero-Pérez, María Olga[et al.] (Elsevier, 2024)
The present study optimizes Cu-supported catalysts on hydrotalcite for the synthesis of n-butanol whose interest is in its use as biofuel, due to its superior performance in comparison with other short-chain alcohols. ...